Abstract
The compressibilities of seven liquidphase, macrocyclic host-guest systems were determinedat approximately 25 °C and 3.4 × 107 Pa.Each two-component system consisted of a cyclodextrin,a calixarene, or a crown ether as host and anappropriate solvent as guest. In each case studied,the host-guest system was found to be lesscompressible than the pure solvent, with thedifferences ranging from ∼2 to ∼18% of the magnitudesof the pure solvent compressibilities. These findingshave enabled us to better understand how strong,ambient pressure, intermolecular host–guestinteractions influence the compressibility ofsolutions. Both inclusion and solvationcontribute.
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Busch, D.H., Roesner, R.A., Allison, T.L. et al. The Compressibilities of Liquid Phase Host-Guest Systems. Journal of Inclusion Phenomena 30, 185–196 (1998). https://doi.org/10.1023/A:1007918108148
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DOI: https://doi.org/10.1023/A:1007918108148