Skip to main content
SpringerLink
Log in

New routes to carbonyl complexes of general formula [RuCl2(CO)(S)(PPh3)2] (S = DMA, DMF, DMSO): crystal structure of [RuCl2(CO)(DMA)(PPh3)2] · 1/2CH2Cl2

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

The compound [RuCl2(CO)(DMA)(PPh3)2] [DMA = dimethylacetamide] was obtained from [RuCl3(PPh3)2-(DMA)] · DMA and CO in DMA. Orange crystals of [RuCl2(CO)(DMA)(PPh3)2] · 1/2CH2Cl2 were isolated by slow evaporation of a CH2Cl2/DMA solution and its structure was determined by single crystal X-ray diffraction. The analogous compounds containing DMF and DMSO were obtained from the precursor ttt-[RuCl2(CO)2(PPh3)2]. Characterization of the other complexes is based on i.r. and n.m.r. spectroscopy, including 31P{1H} data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E.A. Seddon and K.R. Seddon, The Chemistry of Ruthenium, Elsevier, Amsterdam, 1984.

    Google Scholar 

  2. B.R. James, L.K. Thompson and D.K.W. Wang, Inorg. Chim. Acta, 29, L237 (1978); T.W. Dekleva, I.S. Thorburn and B.R. James, Inorg. Chim. Acta, 100, 49 (1985).

    Google Scholar 

  3. A.A. Batista, O.M. Porcu, O.R. Nascimento, V.M. Barbosa and G. Oliva, J. Coord. Chem., 30, 345 (1993); I.S. Thorburn, S.J. Rettig and B.R. James, Inorg. Chem., 25, 234 (1986).

    Google Scholar 

  4. B.R. James, L.D. Markham, B.C. Hui and G.L. Rempel, J. Chem. Soc., Dalton Trans., 2247 (1973).

  5. Enraf-Nonius. CAD-4-PC. Version 1.2, Enraf-Nonius: Delft, The Netherlands, 1993.

    Google Scholar 

  6. K. Harms and S. Wocadlo. XCAD-4. Program for Processing CAD-4 Diffractometer Data. University of Marburg: Marburg, Germany, 1995.

    Google Scholar 

  7. G.M. Sheldrick. SHELXS-97. Program for Crystal Structure Resolution. Univ. Göttingen: Göttingen, Germany, 1997.

    Google Scholar 

  8. G.M. Sheldrick. SHELXL-97. Program for Crystal Structures Analysis. Univ. Göttingen: Göttingen, Germany, 1997.

    Google Scholar 

  9. L.J. Farrugia. ORTEP3 for Windows. J. Appl. Crystallogr., 30, 565 (1997).

    Google Scholar 

  10. D.T. Cromer and J.B. Mann, Acta Crystallogr., A24, 321 (1968).

    Google Scholar 

  11. T.A. Stephenson and G. Wilkinson, J. Inorg. Nucl. Chem., 28, 945 (1966).

    Google Scholar 

  12. D.A. Perrin, W.L.F. Amarrego and D.F. Perrin, Purification of Laboratory Chemicals, 1st edit., New York, Pergamon Press, 1966.

    Google Scholar 

  13. K. Wohnrath, A.A. Batista, A.G. Ferreira, J. Zukerman-Schpector, L.A.A. De Oliveira and E.E. Castellano, Polyhedron, 17, 2013 (1998).

    Google Scholar 

  14. L.M. Wilkes, J.H. Nelson, J.P. Mitchener, M.W. Babich, W.C. Riley, B.J. Helland, R.A. Jacobson, M.Y. Cheng, K. Seff and L.B. McCusker, Inorg. Chem., 21, 1376 (1982).

    Google Scholar 

  15. F.A. Coton and G. Wilkinson, Advanced Inorganic Chemistry, 5th edit., Wiley-Interscience, Toronto, 1988, p. 1299.

    Google Scholar 

  16. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th edit., England, 1997.

  17. M.G. Bhowon, H.L.K. Wah, R. Narain, Polyhedron, 18, 341 (1998); M.B. Egorova, A.V. Drobachenko and A.M. Popov, Koordinatsionnaya Khimiya, 13, 541 (1987); N.P.G. Roeges, A Guide to the Interpretation of Infrared Spectra of Organic Structures. Wiley, England, 1994.

    Google Scholar 

  18. P. Ford, D.F. Rudd, R. Gaunder and H. Taube, J. Am. Chem. Soc., 90, 1187 (1968).

    Google Scholar 

  19. A.M. Zwickel and C. Creuz, Inorg. Chem., 10, 2395 (1971).

    Google Scholar 

  20. J. Chakravarty and S. Bhattacharya, Polyhedron, 13, 2671 (1994).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Departamento de Química, Universidade Federal de São Carlos, CEP 13.565-905 –, C.P. 676 –, São Carlos (SP), Brazil

    Alzir A. Batista, Karen Wonrath, Salete L. Queiroz & Ornella M. Porcu

  2. Instituto de Física de Sao Carlos –, Universidade de São Paulo –, CEP 13.560-970 –, C.P. 369 –, São Carlos (SP), Brazil

    Eduardo E. Castellano & Claudio Barberato

Authors
  1. Alzir A. Batista
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Karen Wonrath
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Salete L. Queiroz
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ornella M. Porcu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Eduardo E. Castellano
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Claudio Barberato
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Batista, A.A., Wonrath, K., Queiroz, S.L. et al. New routes to carbonyl complexes of general formula [RuCl2(CO)(S)(PPh3)2] (S = DMA, DMF, DMSO): crystal structure of [RuCl2(CO)(DMA)(PPh3)2] · 1/2CH2Cl2. Transition Metal Chemistry 26, 365–368 (2001). https://doi.org/10.1023/A:1007129529341

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1007129529341

Keywords

Search

Navigation