Abstract
Reaction of CuII salts with phenanthroline and oxalate (ox) or oxamate (oxm) gives [Cu(phen)(ox)(H2O)] · H2O or [Cu(phen)(oxm)(H2O)] · H2O complexes while direct treatment of CuII salts with oxalate or oxamate gives [NH4]2[Cu(ox)2] and [Cu(oxm)2(H2O)2] respectively. The X-ray structures of one example of each system, aquo-oxamato-phenanthroline-copper(II)-dihydrate and the polymeric ammonium-bis(aquo)-tetraoxalato-dicopper(II)-dihydrate, are reported.
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Novosad, J., Messimeri, A.C., Papadimitriou, C.D. et al. Copper(II) oxalate and oxamate complexes. Transition Metal Chemistry 25, 664–669 (2000). https://doi.org/10.1023/A:1007068914946
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DOI: https://doi.org/10.1023/A:1007068914946