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Solution studies on trace metal ion interactions with adenine as primary ligand and 5-halouracils as secondary ligands

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Abstract

The interaction of trace metal ions, viz. MnII, CoII, NiII, CuII, ZnII and CdII with adenine (A) as primary ligand and 5-halouracils, viz. 5-bromouracil (5BrU) and 5-iodouracil (5IU) as secondary ligands (L) has been studied at 25±0.1°C and at constant ionic strength (μ=0.1M NaNO3), in an aqueous medium using Bjerrum–Calvin's pH-titration technique as adopted by Irving and Rossotti for binary (ML), and by Chidambaram and Bhattacharya for ternary (MAL) systems respectively. The experimental pH-titration data were analyzed with the aid of the BEST computer program in order to evaluate formation constants of various intermediate complex species formed in binary and ternary systems involving nucleobases (viz. A, 5BrU and 5IU). The relative stability of each ternary complex was compared with that of the corresponding binary complexes in terms of ΔlogK values.

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Authors and Affiliations

  1. Department of Chemistry, Banaras Hindu University, Varanasi-, 221005, India

    Sudha Singh

  2. Department of Chemistry, University of Roorkee, Roorkee-, 247667, India

    Rajender Singh, Preeti Babbar & Udai P. Singh

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  1. Sudha Singh
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  2. Rajender Singh
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  3. Preeti Babbar
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Singh, S., Singh, R., Babbar, P. et al. Solution studies on trace metal ion interactions with adenine as primary ligand and 5-halouracils as secondary ligands. Transition Metal Chemistry 25, 9–16 (2000). https://doi.org/10.1023/A:1007061109703

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