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Ruthenium(III) mono (2,2′-bipyridine) complexes containing O,O-donor ligands and their oxidation properties for organic compounds

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Abstract

The new complexes [RuIIIbpyL2](PF6) and [RuIIIbpyL′Cl2] [bpy = 2,2′-bipyridine; HL = acetylacetone, trifluoroacetylacetone, benzoylacetone (Hbac), tropolone or maltol; HL′ = Hbac or dibenzoylmethane) have been prepared and characterized by spectroscopy. Their redox behaviour was studied by cyclic voltammetry. They effectively catalyze the oxidation of alcohols, alkanes and primary aromatic amines.

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References

  1. F.P. Dwyer, H.A. Goodwin and E.C. Gyarfas, Aust. J. Chem., 16, 42 (1963).

    Google Scholar 

  2. G.M. Bryant and J.E. Fergusson, Aust. J. Chem., 24, 275 (1971).

    Google Scholar 

  3. N. Ghatak and S. Bhattacharya, Transition Met. Chem., 21, 423 (1996).

    Google Scholar 

  4. N.C. Pramanik and S. Bhattacharya, Polyhedron, 16, 3047 (1997).

    Google Scholar 

  5. N.C. Pramanik and S. Bhattacharya, Polyhedron, 16, 1755 (1997).

    Google Scholar 

  6. A.M. El-Hendawy, A.H. Al-Kubaisi and H.A. Al-Madfa, Polyhedron, 16, 3039 (1997).

    Google Scholar 

  7. S. Anderson and K.R. Seddon, J. Chem. Res. (S), 74 (1979).

  8. J. Chatt, G.J. Leigh, D.M.P. Mingos and R. Paske, J. Chem. Soc. (A), 2636 (1968).

  9. A.M. El-Hendawy, A. El-Kourashy and M.M. Shanab, Poly-hedron, 11, 523 (1992).

    Google Scholar 

  10. M.M. Finnegan, T.G. Lutz, W.O. Nelson, A. Smith and C. Orvig, Inorg. Chem., 26, 2171 (1987).

    Google Scholar 

  11. G.T. Behnke and K. Nakamoto, Inorg. Chem., 6, 433 (1967).

    Google Scholar 

  12. A.M. El-Hendawy, Polyhedron, 9, 2309 (1990).

    Google Scholar 

  13. W.P. Griffith, C.A. Pumphrey and C.A. Skapski, Polyhedron, 6, 891 (1987).

    Google Scholar 

  14. D.W. Raichart and H. Taube, Inorg. Chem., 11, 999 (1972).

    Google Scholar 

  15. A.M. El-Hendawy, W.P. Griffith, M.N. Moussa and F.I. Taha, J. Chem. Soc., Dalton Trans., 901 (1989).

  16. A.M. El-Hendawy and M.S. El-Shahawi, Polyhedron, 8, 2813 (1989).

    Google Scholar 

  17. A.M. El-Hendawy, Polyhedron, 10, 2511 (1991).

    Google Scholar 

  18. O.K. Medhi and U. Agarwala, J. Inorg. Nucl. Chem., 1413 (1980).

  19. A.M. El-Hendawy, Inorg. Chim. Acta, 179, 223 (1991).

    Google Scholar 

  20. S.P. Copper, Y.B. Koh and K.N. Raymond, Inorg. Chem., 104, 5092 (1982).

    Google Scholar 

  21. R.B. Von Dreele and R.C. Fay, J. Am. Chem. Soc., 94, 7935 (1972).

    Google Scholar 

  22. T.W. Hambley, C.J. Hawkins and T.A. Kabanos, Inorg. Chem., 26, 3740 (1987).

    Google Scholar 

  23. C.J. Hawkins and T.A. Kabanos, Inorg. Chem., 28, 1084 (1989).

    Google Scholar 

  24. G.M. Bryant, J.E. Fergusson and H.K.J. Powell, Aust. J. Chem., 24, 257 (1971).

    Google Scholar 

  25. M.A. Queiros and S.D. Robinson, Inorg. Chem., 17, 310 (1978).

    Google Scholar 

  26. D. Gussoni, G. Mercati and F. Morazzoni, Gazz. Chem. Ital., 109, 545 (1979).

    Google Scholar 

  27. J.H. Tocher and J.P. Fackler, Inorg. Chim. Acta, 102, 211 (1985).

    Google Scholar 

  28. R.S. Nicholson and I. Shain, Anal. Chem., 36, 706 (1964).

    Google Scholar 

  29. P.K. Sinha, J. Chakravarty and S. Bhattacharya, Polyhedron, 16, 81 (1997).

    Google Scholar 

  30. N.E. Tokel-Takvorian, R.E. Hemingway and A.J. Bird, J. Am. Chem. Soc., 95, 6582 (1973).

    Google Scholar 

  31. N.C. Pramanik and S. Bhattacharya, J. Chem. Research(S), 98 (1997).

  32. Y. Tsuji, T. Ohta, T. Ido, H. Minbu and Y. Watanabe, J. Organometal. Chem., 270, 333 (1984).

    Google Scholar 

  33. S.I. Murahashi, Y. Oda, T. Naota and T. Kuwabara, Tetrahedron Lett., 34, 1299 (1993).

    Google Scholar 

  34. W.P. Griffith and A.F. Shoair, Unpublished work.

  35. W.P. Griffith, B. Reddy, A.F. Shoair, M. Suriaatmoja, A.J.P. White and D.J. Williams, J. Chem. Soc., Dalton Trans., 2819 (1998).

  36. R. Tang, S.E. Diamond, N. Neary and F. Mares, J. Chem. Soc. Chem. Commun., 562 (1978).

  37. A.J. Bailey and B.R. James, Chem. Commun., 2343 (1996); 506 (1997).

  38. A. Butler, M.J. Clangue and G.E. Meister, Chem. Rev., 94, 625 (1994).

    Google Scholar 

  39. G. Barak, J. Dakka and Y. Sasson, J. Org. Chem., 53, 3553 (1988).

    Google Scholar 

  40. A.S. Goldstein, R.H. Beer and R.S. Drago, J. Am. Chem. Soc., 116, 2424 (1994).

    Google Scholar 

  41. C. Che, W. Tang, M.H. Lam and T.C.W. Mak, J. Chem. Soc., Dalton Trans., 2885 (1988).

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, University of Qatar, P.O. Box 2713, Doha, Qatar

    Ahmed M. El-Hendawy, Siham Y. Alqaradawi & Homaid A. Al-Madfa

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  1. Ahmed M. El-Hendawy
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  2. Siham Y. Alqaradawi
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  3. Homaid A. Al-Madfa
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El-Hendawy, A.M., Alqaradawi, S.Y. & Al-Madfa, H.A. Ruthenium(III) mono (2,2′-bipyridine) complexes containing O,O-donor ligands and their oxidation properties for organic compounds. Transition Metal Chemistry 25, 572–578 (2000). https://doi.org/10.1023/A:1007059402050

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