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Structure and properties of di-μ-acetato-dichlorobis(2,2′-bipyridine)dirhodium(II)-trihydrate

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Abstract

Reduction of [Rh2(μ-OAc)2(bpy)2(H2O)2](OAc)2 and [Rh2Cl2(μ-OAc)2(bpy)2] · 3H2O complexes with ethanol and [Cr2(OAc)4(H2O)2] has been investigated using e.p.r. and u.v.–vis. spectra. The results indicate that stable complexes containing the [Rh2 3+] entity are not formed. The X-ray structure of [Rh2Cl2(μ-OAc)2(bpy)2] · 3H2O has been determined. Coordination around the Rh atom is in the form of a distorted octahedron. The complex shows an almost ideal eclipsed conformation. The equatorial coordination sites are occupied by bridging carboxylato ligands and 2,2′-bipyridine and axial positions by the Cl ligand and the rhodium atom. The Rh–Rh distance is 2.574 Å.

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References

  1. 1.

    F.A. Cotton and R.A. Walton, Multiple Bonds between Metal Atoms, Clarendon Press, Oxford, 1993; E.B. Boyar and S.D. Robinson, Coord. Chem. Rev., 50, 109 (1983); T.R. Felthouse, Progr. Inorg. Chem., 29, 73 (1982).

  2. 2.

    F.P. Pruchnik, Pure Appl. Chem., 61, 795 (1989).

  3. 3.

    F.P. Pruchnik, B.R. James and P. Kvintovics, Can. J. Chem., 64, 936 (1986); F.P. Pruchnik, M. Zuber, H. Pasternak and K. Wajda, Spectrochim. Acta, 34A, 1111 (1978); F.P. Pruchnik, J. Hanuza, K. Hermanowicz, K. Wajda-Hermanowicz and M. Zuber, ibid.; 45A, 835 (1989); F.P. Pruchnik and M. Zuber, Rocz. Chem., 51, 1813 (1977); A. Szymaszek and F.P. Pruchnik, Polish J. Chem., 66, 1859 (1992).

  4. 4.

    H. Pasternak and F.P. Pruchnik, Inorg. Nucl. Chem. Letters, 12, 591 (1976).

  5. 5.

    F.P. Pruchnik, A. Jezierski and E. Kalecińska, Polyhedron, 10, 2551 (1991).

  6. 6.

    T. Gøowiak, F.P. Pruchnik and M. Zuber, Polish J. Chem., 65, 1749 (1991).

  7. 7.

    F.P. Pruchnik, F. Robert, Y. Jeannin and S. Jeannin, Inorg. Chem., 35, 4261 (1996).

  8. 8.

    L. Natkaniec and F.P. Pruchnik, J. Chem. Soc. Dalton Trans., 3261 (1994).

  9. 9.

    J. Halpern, E. Kimura, J. Molin-Case and C.S. Wong, J. Chem. Soc., Chem. Commun., 1207 (1971).

  10. 10.

    L. Trynda and F.P. Pruchnik, J. Inorg. Biochem., 58, 69 (1995); F.P. Pruchnik and D. Duś, J. Inorg. Biochem., 61, 55 (1996); F.P. Pruchnik and D. DusÂ, II Symposium on Inorganic Biochemistry and Molecular Biophysics, Proceedings, p. 281, Wrocøaw 1989; F.P. Pruchnik, G. Kluczewska, A. Wilczok, U. Mazurek and T. Wilczok, J. Inorg. Biochem., 65, 25 (1997); A. Wilczok, Biological Activity of Rhodium Complexes in Synchronous Culture of Chlorella vulgaris. Ph.D. Thesis, Silesian Academy of Medicine, Katowice 1990; F.P. Pruchnik, M. Bień, and T. Lachowicz, Metal-Based Drugs, 3, 185 (1996); M. Bień, T.M. Lachowicz, A. Rybka, F.P. Pruchnik and L. Trynda, Metal-Based Drugs, 4, 81 (1997).

  11. 11.

    L. Trynda-Lemiesz and F.P. Pruchnik, J. Inorg. Biochem., 66, 187 (1997).

  12. 12.

    H. Pasternak, E. Lancman and F.P. Pruchnik, J. Mol. Catal., 29, 13 (1985); H. Pasternak, F.P. Pruchnik, K. Wajda-Hermanowicz and M. Zuber, Polish J. Chem., 63, 619 (1986); H. Pasternak and F.P. Pruchnik, ibid., 66, 865 (1992).

  13. 13.

    M.P. Doyle, in Catalytic Asymmetric Synthesis, I. Ojima, ed., VCH Publishers, New York, 1993, chapter 3; M.P. Doyle, M.N. Protopopova, Q.-L. Zhou and J.W. Bode, Tetrahedron: Asymmetry, 6, 2157 (1995); M.P. Doyle and Q.-L. Zhou, J. Org. Chem., 60, 6654 (1995); M.P. Doyle, Chem. Rev., 86, 919 (1986); M.P. Doyle, Acc. Chem. Res., 19, 348 (1986); A. Padwa, D.J. Austin and S.F. Hornbuckle, J. Org. Chem., 61, 63 (1996); A.G.H. Wee and B. Liu, Tetrahedron Lett., 37, 145 (1996); S. Miah, A.M.Z. Slawin, C.J. Moody, S.M. Sheehan, J.P. Marino, M.A. Semones, A. Padwa and I.C. Richards, Tetrahedron, 52, 2489 (1996).

  14. 14.

    J.L. Bear, H.B. Gray Jr., L. Rainen, I.M. Chang, R. Howard, G. Serio and A.P. Kimball, Cancer Chemother. Rep. 59, 611 (1975); R.A. Howard, A.P. Kimball and J.L. Bear, Cancer Res., 39, 2568 (1979).

  15. 15.

    C.A. Crawford, J.H. Matonic, J.C. Huffman, K. Folting, K.R. Dunbar and G. Christou, Inorg. Chem., 36, 2361 (1997); K.V. Catalan, D.J. Mindiola, D.L. Ward and K.R. Dunbar, Inorg. Chem., 36, 2458 (1997); K.R. Dunbar, J.H. Matonic, V.P. Saharan, C.A. Crawford and G. Christou, J. Am. Chem. Soc., 116, 2201 (1994); S.P. Perlepes, J.C. Hu.man, J.H. Matonic, K.R. Dunbar and G. Christou, J. Am. Chem. Soc., 113, 2770 (1991); C.A. Crawford, J.H. Matonic, W.E. Streib, J.C. Hu.-man, K.R. Dunbar and G. Christou, Inorg. Chem., 32, 3125 (1993).

  16. 16.

    R.G. Hughes, J.L. Bear and A.P. Kimball, Proc. Am. Assoc. Cancer Res., 13, 120 (1972).

  17. 17.

    P.N. Rao, M.L. Smith, S. Pathak, R.A. Howard and J.L. Bear, J. Nat. Cancer Inst., 64, 905 (1980).

  18. 18.

    L.M. Hall, R.J. Speer and H.J. Ridgway, J. Clin. Hematol. Oncol., 10, 25 (1980).

  19. 19.

    E. Tselepi-Kalouli and N. Katsaros, J. Inorg. Biochem., 40, 95 (1990).

  20. 20.

    L.D. Dale, T.M. Dyson, D.A. Tocher and D.I. Edwards, Anticancer Drug Res., 4, 295 (1989).

  21. 21.

    S. Zyngier, E. Kimura and R. Najjar, Braz. J. Med. Biol., 22, 397 (1989).

  22. 22.

    E.M. Reibscheid, S. Zyngier, D.A. Maria, R.J. Mistrone, R.D. Sinnistera, L.G. Couto and R. Najjar, Braz. J. Med. Biol. Res., 27, 91 (1994).

  23. 23.

    M.S. Nothenberg, G.K. Takeda and J. Najjar, J. Inorg. Biochem., 42, 217 (1991).

  24. 24.

    R.C. Richmond, N.P. Farrel and H.K. Mathani, Radiation Res., 120, 403 (1989); R.C. Richmond, H.K. Mathani, Radiation Res., 127, 36 (1991).

  25. 25.

    R. Chibber, I.J. Stratford, P. O'Neil, P.W. Sheldon, I. Ahmed and R. Lee, Int. J. Radiation Biol., 84, 513 (1985).

  26. 26.

    G.L. Rempel, P. Legzdins, H. Smith and G. Wilkinson, Inorg. Synth., 13, 90 (1972).

  27. 27.

    E. Gaødecka, Acta Crystallogr., 52, C44 (1996).

  28. 28.

    E. Gaødecka, J. Appl. Crystallogr., 827, 32 (1996).

  29. 29.

    G.M. Sheldrick, SHELXTL-PC, version 4.2. An Integrated system for solving refining and displaying crystal structures from diffraction data; Siemens Analytical X-ray Instruments, INC.; Madison, WI, 1990.

  30. 30.

    I. Vickovic, J. Appl. Cryst., 21, 987 (1988).

  31. 31.

    V.M. Miskowski, I.S. Sigal, K.R. Mann, H.B. Gray, S.J. Milder, G.S. Hammond and P.R. Ryason, J. Am. Chem. Soc., 101, 4383 (1979).

  32. 32.

    V.M. Miskowski, G.L. Nobinger, D.S. Kliger, G.S. Hammond, N.S. Lewis, K.R. Mann and H.B. Gray, J. Am. Chem. Soc., 100, 485 (1978).

  33. 33.

    I.S. Sigal and H.B. Gray, J. Am. Chem. Soc., 103, 2220 (1981).

  34. 34.

    N.S. Lewis, K.R. Mann, J.G. Gordon II and H.B. Gray, J. Am. Chem. Soc., 98, 7461 (1976).

  35. 35.

    V.I. Sokol, M.A. Porai-Koshits, A.P. Kochetkova and L.B. Sveshnikova, Koord. Khim., 10, 844 (1984).

  36. 36.

    M. Calligaris, L. Campana, G. Mestroni, M. 1Torantore and E. Alessio, Inorg. Chim. Acta, 127, 103 (1987).

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Gałdecka, E., Gałdecki, Z., Pruchnik, F.P. et al. Structure and properties of di-μ-acetato-dichlorobis(2,2′-bipyridine)dirhodium(II)-trihydrate. Transition Metal Chemistry 25, 315–319 (2000). https://doi.org/10.1023/A:1007053619224

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Keywords

  • 3H2O
  • Inorganic Chemistry
  • Rhodium
  • Stable Complex
  • Bipyridine