Abstract
Rate constants for the reaction of [Fe(CN)5(H2O)]−3 with [Co(NH3)5(pyrazine)]3+ have been analysed on the basis of a pre-association equilibrium constant and a rate constant for the subsequent ligand interchange. The latter represents an unusual parameter, a rate constant for water loss from a low-spin iron(II) centre.
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Muriel, F., Sánchez, F. & Burgess, J. Rate constant for water loss from low-spin iron(II) in aquapentacyanoferrate(II). Transition Metal Chemistry 25, 537–540 (2000). https://doi.org/10.1023/A:1007043315408
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DOI: https://doi.org/10.1023/A:1007043315408