Abstract
The novel cobalt(II) and nickel(II) complexes with 4-(p-methoxyphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole (MOBPT) have been synthesized and their molecular structures determined by X-ray analysis, i.r. and by ESI-MS spectroscopy. The metal atom is in a distorted octahedral environment. Two bidentate chelating ligands (MOBPT) coordinate to the metal center equatorially and two water molecules coordinate axially. Each MOBPT entity coordinates via one triazole nitrogen and one pyridine nitrogen atom. Magnetic measurements show that the complexes are high-spin species in the 75–300 K range.
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References
A. Bencini, D. Gatteschi, C. Zanchini, J.G. Haasnoot, R. Prins and J. Reedijk, J. Am. Chem. Soc., 109, 2926 (1987).
P.J. van Koningsbruggen, D. Gatteschi, R.A.G. de Graa., J.G. Haasnoot, J. Reedijk and C. Zanchini, Inorg.Chem., 34, 5175 (1995).
N. Moliner, M.C. Munoz, P.J. van Koningsbruggen and J.A. Real, Inorg. Chim. Acta, 274, 1 (1998).
Y. Garcia, P.J. van Koningsbruggen, E. Codjovi, R. Lapouyade, O. Kahn and L. Rabardel, J. Mater. Chem., 7, 857 (1997).
O. Kahn and C.J. Martinez, Science, 279, 44 (1998).
Z.X. Wang, Z.P. Bai, J.X. Yang, K.I. Okamoto and X.Z. You, Acta Crystallogr., C54, 438 (1998).
W. Chen, Z.X. Wang, F.F. Jian, Z.P. Bai and X.Z. You, Acta Crystallogr., C54, 851 (1998).
H.-K. Fun, K. Chinnakali, S.C. Shao, D.R. Zhu and X.Z. You, Acta Crystallogr., C55, 770 (1999).
F.S. Keij, R.A.G. de Graa., J.G. Haasnoot and J. Reedijk, J. Chem. Soc., Dalton Trans., 2093 (1984).
S.C. Shao, D.R. Zhu, X.H. Zhu, X.Z. You, S.S.S. Raj and H.-K. Fun, Acta Crystallogr., C55, 1412 (1999).
C. Faulmann, P.J. van Koningsbruggen, R.A.G. de Graa., J.G. Haasnoot and J. Reedijk, Acta Crystallogr., C46, 2357 (1990).
U. Hartmann and H. Vahrenkamp, Inorg. Chim. Acta, 239, 13 (1995).
J.P. Cornelissen, J.H. van Diemen, L.R. Groeneveld, J.G. Haasnoot, A.L. Spek and J. Reedijk, Inorg. Chem., 31, 198 (1992).
P.J. Kunkeler, P.J. van Koningsbruggen, J.P. Cornelissen, A.N. van der Horst, A.M. van der Kraan, A.L. Spek, J.G. Haasnoot and J. Reedijk, J. Am. Chem. Soc., 118, 2190 (1996).
P.J. van Koningsbruggen, K. Goubitz, J.G. Haasnoot and J. Reedijk, Inorg. Chim. Acta, 268, 37 (1998).
P.B. Viossat, N.-H. Dung, J.-C. Lancelot and M. Robba, Acta Crystallogr., C40, 935 (1984).
S.W. Peterson and H.A. Levy, Acta Crystallogr., 10, 70 (1957).
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds. Wiley, New York, 1970, p. 166.
B.J. Hathaway and A.A.G. Tomlinson, Coord. Chem. Rev., 5, 1 (1970).
M.M. da Mota, J. Rodgers and S.M. Nelson, J. Chem. Soc. A, 2036 (1969).
V. Katta, S.K. Chowdhury and B.T. Chait, J. Am. Chem. Soc. 112, 5348 (1990).
S.R. Wilson, A. Yasmin and Y. Wu, J. Org. Chem., 57, 6941 (1992).
R. Arakama, T. Matuo, H. Ito, I. Katakuse, K. Nozaki, T. Ohno and M. Haga, Org. Mass Spectrom., 29, 289 (1994).
E. Kwaskowska-Che?, M. Kubiak, T. Glowiak and J.J. Ziólk-owski, Transition Met. Chem., 23, 641 (1998).
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Zhu, D., Song, Y., Liu, Y. et al. Syntheses, crystal structures and spectroscopic properties of the novel complexes [M(MOBPT)*2 (H2O)2](ClO4)2 · 4H2O (M = CoII and NiII). Transition Metal Chemistry 25, 589–593 (2000). https://doi.org/10.1023/A:1007037326099
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DOI: https://doi.org/10.1023/A:1007037326099