Abstract
Three Schiff base copper(II) complexes have been prepared and characterized by elemental analysis, mass spectra, i.r., electronic spectra, μeff and X-ray crystal structures. Cyclic voltammetry studies on the complexes indicate a dependence of the cathodic potentials upon electronic effects, but independence on the solid state structure.
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R.H. Holm and M.J. O'Connor, Prog. Inorg. Chem., 14, 241 (1971).
H.S. Maslen and T.N. Waters, Coord. Chem. Rev., 17, 137 (1975).
G.V. Panova, N.K. Vikulova and V.M. Potapov, Russian Chem. Rev., 49, 655 (1980).
A.D. Garnovskii, A.L. Nivorozhin and V.I. Minkin, Coord. Chem. Rev., 126, 1 (1993).
P.L. Orioli and L. Sacconi, J. Am. Chem. Soc., 88, 277 (1966).
N. M tsumoto, Y. Nonaka, S. Kida, S. Kawano and I. Ueda, Inorg. Chim. Acta, 37, 27 (1979).
J.M. Fernández-G., M.J. Rosales-Hoz, M.F. Rubio-Arroyo, R. Salcedo, R.A. Toscano and A. Vela, Inorg. Chem., 26, 349 (1987); J.M. Fernêndez-G., M.R. Patiño-Maya, R.A. Toscano, L. Velasco, M. Otero-López and M. Aguilar-Martínez, Polyhedron, 16, 4371 (1997).
J.R. Wasson, H.W. Richardson and W.E. Hatfield, Z. Naturforsch., B32, 551 (1977).
M.L. Khorana and S.Y. Pandit, J. Indian Chem. Soc., 40, 789 (1963).
G.L. Eichhorn and M.D. Marchand, J. Am. Chem. Soc., 78, 2688 (1956).
R.S. Nicholson and I. Shain, Anal. Chem., 36, 706 (1964); W.E. Geiger, Prog. Inorg. Chem., 33, 275 (1985).
D.T. Sawyer and J.L. Roberts. Experimental Electrochemistry for Chemists. Wiley, New York, 1974. Ch. 7. p. 301.
International Tables for X-ray Crystallography, A.J.C. Wilson (Ed.) Kluwer Academic Publishers, Dordrecht. 1992: Tables 4.2.6.8 (pp. 219-222) and 6.1.1.4 (pp. 500-502)
A. Altomare, G. Cascarano, C. Giacovazzo, A. Guagliardi, M.C. Burla, G. Polidori and M. Camalli, J. Appl. Cryst., 27, 435 (1994).
G.M. Sheldrick. SHELXL97 Program for Refinement of Crystal Structures. University of Gottingen, Germany 1997.
M. Takayama, Y. Tanaka and T. Nomura, Org. Mass Spectrom., 28, 1529 (1993).
L. Sacconi and M. Ciampolini, J. Chem. Soc., 276 (1964).
J.E. Kovacic, Spectrochim. Acta, 23A, 183 (1967).
G.S Patterson and R.H. Holm, Bioinorg. Chem., 4, 257 (1975).
J.M. Fernández-G, E. Acevedo-Arauz, R. Cetina-Rosado, R.A. Toscano, N. Macías-Ruvalcaba and M. Aguilar-Martínez, Transition Met. Chem., 24, 18 (1999).
J. C utchler, R. Hynes and E.J. Gabe, Inorg. Chem., 29, 4921 (1990).
P. Zanello in I. Bernal (Ed.) Stereochemistry of Organometallic and Inorganic Compounds. Vol. 4. Elsevier. Amsterdam, 1991, pp. 181-366.
A.J. Bard and L.R. Faulkner, Electrochemical Methods. Fundamentals and Applications. Wiley, New York, 1980.
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Fernández-G, J.M., Ruíz-Ramírez, O.L., Toscano, R.A. et al. Crystal structures and voltammetric behavior of three copper(II) complexes derived from bulky Schiff bases. Transition Metal Chemistry 25, 511–517 (2000). https://doi.org/10.1023/A:1007028814788
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DOI: https://doi.org/10.1023/A:1007028814788