Abstract
Novel complexing processes in binary systems containing CoIII and 8-mercaptoquinoline or its derivatives (5-Cl-, 5-Br-, 5-Me-, 5-Ph- and 5-SMe- 8-mercaptoquinoline), with a cobalt(III)hexacyanoferrate(II) gelatin-immobilized matrix in contact with an aqueous solution of the corresponding ligand, have been observed. Under the specific conditions described, three water-insoluble coordination compounds are formed in each of the systems indicated, whereas upon complexing in solution or the solid phase the formation of only one complex is observed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
O.V. Mikhailov, Transition Met. Chem., 24, 515 (1999).
O.V. Mikhailov and M.A. Kazymova, Transition Met. Chem., 24, 350 (1999).
O.V. Mikhailov, Russ. J. Coord. Chem., 18, 1008 (1992).
Yu.A. Bankovsky, Chemistry of Inner-complex compounds of 8-mercaptoquinoline and its derivatives. Riga, Zinatne, 1978 (Rus.).
R.J. Pearson, J. Am. Chem. Soc., 85, 3533 (1963).
F.A. Cotton and G.B. Wilkinson, Advanced Inorganic Chemistry, 5th Edit., Wiley, New York, 1990.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Mikhailov, O.V. Cobalt(III)-8-mercaptoquinoline complexing in cobalt(III)hexacyanoferrate(II) gelatin-immobilized matrix systems. Transition Metal Chemistry 25, 341–343 (2000). https://doi.org/10.1023/A:1007003106583
Issue Date:
DOI: https://doi.org/10.1023/A:1007003106583