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Novel tetrahedral and heteronuclear transition metal clusters prepared via single and double isolobal displacements

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Abstract

Ten transition metal cluster complexes with parent and substituted cyclopentadienyl ligands, [(η5-C5H4 CH2CH2)2O][MFeCoS(CO)8]2 (2 M = Mo; 3 M = W), (η5-C5H5)(η5-RC5H4)MFeNiS(CO)5 (5 M = Mo, R = Me; 6 M =  W, R = H), (η5-C5H5)[η5-C5H4C(O)CH2]2[WFeNiS(CO)5][WFeCoS(CO)8] (8), (η5-C5H5)2[η5-C5H4 C(O)CH2]2[WFeNiS(CO)5]2 (9), (η5-RC5H4)[(η5-C5H4CH2CH2)2O][Mo2FeS(CO)7][MoFeCoS (CO)8] (10 R = MeCO; 12 R = MeO2C), (η5-RC5H4)2[(η5-C5H4CH2CH2)2O][Mo2FeS(CO)7]2 (11 R = MeCO; 13 R = MeO2C), were synthesized through single and double isolobal displacements and characterized by elemental analyses, i.r., 1H-n.m.r. and MS techniques.

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Authors and Affiliations

  1. Department of Chemistry, Nankai University, Tianjin, 300071, P.R. China

    Li-Cheng Song, Dian-Shun Guo & Yu-Bin Dong

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  1. Li-Cheng Song
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  2. Dian-Shun Guo
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  3. Yu-Bin Dong
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Song, LC., Guo, DS. & Dong, YB. Novel tetrahedral and heteronuclear transition metal clusters prepared via single and double isolobal displacements. Transition Metal Chemistry 25, 37–40 (2000). https://doi.org/10.1023/A:1007000219737

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