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Synthesis, spectral and magnetic properties of binuclear copper(II)/nickel(II) and copper(II) complexes bridged by glyoximate groups

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Abstract

Three new dinuclear complexes, [(tmen) (H2O)2Ni (Hdmg)(dmg)Cu]·ClO4, [(dien)(H2O)Ni (Hdmg)(dmg) Cu]·ClO4 and [(tmen)Cu(Hdmg)(dmg) Cu] ClO4·H2O (H2dmg=dimethylglyoxime, tmen=tetramethylene diamine), have been prepared. Variable-temperature- magnetic susceptibility measurements (75–300K) on the complexes reveal the presence of intramolecular antiferromagnetic interactions through the oximate bridges. The formation of mononuclear, dinuclear complexes has been confirmed by spectrophotometry.

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Authors and Affiliations

  1. National Laboratory of Molecular and Biomolecular Electronics, Southeast University, Nanjing, 210096, P.R. China

    Shu-zhong Zhan, Qing Dai & Chun-wei Yuan

Authors
  1. Shu-zhong Zhan
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  2. Qing Dai
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  3. Chun-wei Yuan
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Zhan, Sz., Dai, Q. & Yuan, Cw. Synthesis, spectral and magnetic properties of binuclear copper(II)/nickel(II) and copper(II) complexes bridged by glyoximate groups. Transition Metal Chemistry 24, 74–76 (1999). https://doi.org/10.1023/A:1006996319642

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