Abstract
Template condensation of 1,4-phenylenediamine, formaldehyde, 1,3-diaminopropane and benzil in a 1:4:4:2, molar ratio results in the formation of a new series of binuclear decaazamacrocyclic complexes: dichloro/nitrato [1-phenyl bis(8,9-diphenyl-1,3,7,10,14 pentaazacyclo-pentadeca-7,9-diene) metal (II)], [M2LX4](M = MnII, CoII, NiII, CuII and ZnII, X = Cl or NO3), which were characterised by i.r., 1H-n.m.r., e.p.r., u.v–vis. spectral studies, conductivity and magnetic susceptibility measurements. All the complexes show octahedral geometry.
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Khan, T.A., Shagufta, M. Transition metal ion directed bimetallic macrocyclic complexes. Transition Metal Chemistry 24, 669–671 (1999). https://doi.org/10.1023/A:1006991215526
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DOI: https://doi.org/10.1023/A:1006991215526
Keywords
- Physical Chemistry
- Formaldehyde
- Inorganic Chemistry
- Catalysis
- Magnetic Susceptibility