Abstract
The reaction of diethylenetriamine (dien) and 1,2-bis(1,2,4-triazole-1-yl)ethane (btrz) with Cu(ClO4) · 6H2O forms [Cu(dien)(btrz)(ClO4)2] (1), and the reaction of [Cu(en)2(ClO4)2] (en = ethylenediamine) with btrz forms [Cu(en)2(btrz)(ClO4)2] (2). Complexes (1) and (2) were characterized by elemental analysis, i.r., electronic spectroscopy, e.s.r. and magnetic susceptibility. Their crystal structure was determined by X-ray diffraction. In complex (1), Cu is coordinated by a dien and two btrz, forming a distorted CuN5 square pyramid with one btrz bound at the apical position. In complex (2), Cu is coordinated by two en and two nitrogen atoms of btrz forming an elongated octahedron. Both complexes have a one-dimensional chain structure in which btrz ligands bridge between pairs of Cu atom.
Similar content being viewed by others
References
A. Caneschi, D. Gatteschi, J.P. Renard, P. Rey and R. Sessoli, Inorg. Chem., 28, 3314 (1989).
C.T. Chen and K.S. Suslick, Coord. Chem. Rev., 128, 293 (1993).
W. Chiang, D.M. Ho, D.V. Engen and M.E. Thompson, Inorg. Chem., 32, 2886 (1993).
S. Ferrer, J.C. Haasnoot, J. Reedijk, E. Muller, M. Biagini-Cingi, A.M. Manotti-Lanfredi, F. Ugozzoli and C. Foglia, J. Chem. Soc., Dalton Trans., 3029 (1992).
M. Biaginicingi, M. Lanfranchi, A.M. Manotti-Lanfredi, S. Haasnoot and J.G. Reedijk, Inorg. Chim. Acta., 209, 219 (1993).
J. Kriober, J.P. Audiere, R. Claude, E. Codjori, J.G. Haasnoot, F. Groliere, C. Jay and A. Gonthier-Vassal, Chem. Mater., 6, 1404 (1994).
J. Krober, I. Bkouche-Wakeman, C. Pascard, M. Thomann, and O. Kahn, Inorg. Chim. Acta, 230, 159 (1995).
M. Biagini-Cingi, A.M. Manotti-Lanfredi, F. Ugozzoli and J.G. Haasnoot, Inorg. Chim. Acta, 227, 181 (1994).
J. Torres, J.L. Lavandaera, P. Cabildo, R.M. Claramunt and J. Elguero, Heterocyclic Chem., 25, 771 (1988).
T.L. Hennigar, D.C. MacCuarrie, P. Losier, R.D. Rogers and M.J. Zaworotko, Angew. Chem. Int. Ed. Engl., 36, 972 (1997).
C.C. Su and C.Y. Wu, J. Coord. Chem., 33, 1 (1994).
S.J. Liu and C.C. Su, Polyhedron, 15, 1141 (1996).
B.J. Hathaway, G. Wilkinson, R.D. Gillard and J.A. McCleverty (eds), Comprehensive Coordination Chemistry, Vol. 5, Pergamon, Oxford, 1998, pp. 606±610.
A.W. Addison, T.N. Rao, J. Reedijk, J. Van Rijn and G.C. Verschoor, J. Chem. Soc., Dalton Trans., 1349 (1984).
I.M. Procter, B.J. Hathway and P. Nicholls, J. Chem. Soc. (A), 1678 (1968).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Li, B., Xu, Z., Cao, Z. et al. One-dimensional chain copper complexes [Cu(dien)(btrz)(ClO4)2] and [Cu(en)2(btrz)(ClO4)2] based on the bridging ligand 1,2-bis(1,2,4-triazole-1-yl)ethane (btrz). Transition Metal Chemistry 24, 622–627 (1999). https://doi.org/10.1023/A:1006988716200
Issue Date:
DOI: https://doi.org/10.1023/A:1006988716200