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Metallic complexes from 2-furaldehyde semicarbazone and 5-methyl-(2-furaldehyde) semicarbazone

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Abstract

The synthesis and characterization of CoII, NiII, CuII and CdII complexes with 2-furfuralsemicarbazone (FSC) and 5-methyl 2-furfuralsemicarbazone (MFSC) are reported. These ligands lead to the complexes: [ML2X2] or [MLX2] (L = FSC or MFSC) whose structures were determined using elemental analysis, molar conductivity, magnetic measurements, i.r., far i.r. and electronic spectra as well as by n.m.r. FSC and MFSC act as bidentate ligands in most of the CoII, NiII, CuII and CdII complexes. MFSC is a monodentate ligand in [NiBr2(MFSC)4].

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Authors and Affiliations

  1. Université Libanaise, Ramlé, El-Baïda, Beyrouth, Lebanon

    Ghassan Ibrahim & Edmond Chebli

  2. Faculté de Pharmacie, Université d'Angers, Chimie de Coordination, 16 Boulevard Daviers, F-49100, Angers, France

    Mustayeen A. Khan & Gilles M. Bouet

Authors
  1. Ghassan Ibrahim
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  2. Edmond Chebli
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  3. Mustayeen A. Khan
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  4. Gilles M. Bouet
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Ibrahim, G., Chebli, E., Khan, M.A. et al. Metallic complexes from 2-furaldehyde semicarbazone and 5-methyl-(2-furaldehyde) semicarbazone. Transition Metal Chemistry 24, 294–298 (1999). https://doi.org/10.1023/A:1006980908726

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  • DOI: https://doi.org/10.1023/A:1006980908726

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