Skip to main content
SpringerLink
Log in

Synthesis, crystal structure, spectroscopic and thermal investigation of trans-diazido- tetrakis(pyrazole)manganese(II) and trans- diaquadiazidobis(3,4-dimethylpyridine)manganese(II)

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Two mixed ligand MnII complexes, namely trans- diazidotetrakis(pyrazole)manganese(II) (1) and trans-diaquadiazidobis(3,4-dimethylpyridine)manganese(II) (2) have been synthesized and characterized by spectroscopic and crystallographic methods. The i.r. and Raman spectra are reported and correlated with the structures of both complexes. The e.s.r. spectra of the solid complexes and their solutions are reported. Both complexes are monomeric, with distorted octahedral coordination and terminal azide. The thermal decomposition of both complexes was investigated derivatographically.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. A. S. Goher and M. A. M. Abu-Youssef, Acta Chim. Hung., 124, 749 (1987).

    Google Scholar 

  2. F. A. Mautner and M. A. S. Goher, Cryst. Res. Technol., 25, 1271 (1990).

    Google Scholar 

  3. M. A. S. Goher and F. A. Mautner, Croat. Chim. Acta, 63, 559 (1990).

    Google Scholar 

  4. M. A. S. Goher, M. A. M. Abu-Youssef, F. A. Mautner and A. Popitsch, Polyhedron, 11, 2137 (1992).

    Google Scholar 

  5. M. A. S. Goher and F. A. Mautner, Polyhedron, 12, 1863 (1993).

    Google Scholar 

  6. M. A. S. Goher, F. A. Mautner and A. Popitsch, Polyhedron, 12, 2557 (1993).

    Google Scholar 

  7. A. Escuer, R. Vicente, M. A. S. Goher and F. A. Mautner, Inorg. Chem., 34, 5707 (1995).

    Google Scholar 

  8. A. Escuer, R. Vicente, M. A. S. Goher and F. A. Mautner, Inorg. Chem., 35, 6386 (1996).

    Google Scholar 

  9. M. K. Ehlert, A. Storr, R. C. Thompson, F. W. B. Einstein and R. Batchelor, Can. J. Chem., 71, 331 (1993).

    Google Scholar 

  10. M. K. Ehlert, S. J. Retting, A. Storr, R. C. Thompson and J. Trotter, Can. J. Chem., 67, 1970 (1989).

    Google Scholar 

  11. M. K. Ehlert, S. J. Retting, A. Storr, R. C. Thompson and J. Trotter, Can. J. Chem., 69, 432 (1991); M. K. Ehlert, A. Storr and R. C. Thompson, Can. J. Chem. 70, 1121 (1992).

    Google Scholar 

  12. C. J. O'Connor in S. J. Lippard (Ed.), Progress in Inorganic Chemistry, Vol. 29, Wiley, New York, 1982, p.203.

    Google Scholar 

  13. M. A. S. Goher, N. A. Al-Salam and F. A. Mautner, Polyhedron, in press.

  14. N. Walker and D. Stuart, Acta Crystallogr. A39, 158 (1983).

    Google Scholar 

  15. G. M. Sheldrick, SHELXL-93. Universitat Gottingen, Germany, 1993.

    Google Scholar 

  16. G. M. Sheldrick, SHELXS-86. Universitat Gottingen, Germany, 1986.

    Google Scholar 

  17. SHELXTL/PC v.5.03, Simens Analytical Automation Inc., Mad-ison. WI (1995).

  18. A. L. Spek in D. Sayre (Ed.), Computational Crystallography, Clarendon Press, Oxford, 1982, p. 528.

    Google Scholar 

  19. A. J. C. Wilson (Ed.), International Tables for Crystallography, Vol. C, Kluwer Academic Publishers, Dordrecht, 1992, Tables 4.2. 6.8 and 6.1. 1.4.

    Google Scholar 

  20. R. F. Ziolo, M. Allen, D. D. Titus, H. B. Gray and Z. Dori, Inorg. Chem., 11, 3044 (1972).

    Google Scholar 

  21. A. P. Gaughan, R. F. Ziolo and Z. Dori, Inorg. Chem., 10, 2776 (1971).

    Google Scholar 

  22. I. Agrell, Acta Chem. Scand., 25, 1630 (1971).

    Google Scholar 

  23. M. A. S. Goher, Acta Chim. Hung., 127, 213 (1990).

    Google Scholar 

  24. R. C. Dave and R. S. Czernuszewicz, J. Coord. Chem., 33, 257 (1994).

    Google Scholar 

  25. R. S. Czernuszewicz, W. F. Wadner, G. B. Ray and K. Nakamoto, J. Mol. Struct., 242, 99 (1991).

    Google Scholar 

  26. B. R. Srinivasan and S. Saker, Inorg. Chem., 29, 3898 (1990).

    Google Scholar 

  27. T. S. Lobana and N. Bala, Transition Met. Chem., 19, 115 (1994); G. Batra and P. Mathur, Transition Met. Chem., 19, 160 (1994).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Kuwait University, P.O. Box 5969, Safat, 13060, Kuwait

    Mohamed A. S. Goher

  2. Institut fur Physikalische und Theoretische Chemie, Technische Universität Graz, A-8010, Graz, Austria

    Franz A. Mautner & Morsy A. M. Abu-Youssef

Authors
  1. Mohamed A. S. Goher
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Franz A. Mautner
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Morsy A. M. Abu-Youssef
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Goher, M.A.S., Mautner, F.A. & Abu-Youssef, M.A.M. Synthesis, crystal structure, spectroscopic and thermal investigation of trans-diazido- tetrakis(pyrazole)manganese(II) and trans- diaquadiazidobis(3,4-dimethylpyridine)manganese(II). Transition Metal Chemistry 24, 29–34 (1999). https://doi.org/10.1023/A:1006971809550

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1006971809550

Keywords

Search

Navigation