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Complexing of nickel(II) with 8-mercaptoquinoline and of its 5-derivatives in nickel(II)hexacyanoferrate(II) gelatin-immobilized matrix systems

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Abstract

Complexing processes in systems containing NiII and 8-mercaptoquinoline or its derivatives (5-chloro-, 5-bromo-, 5-phenyl, 5-thiomethyl-8-mercaptoquinoline and 5,8-dimercaptoquinoline) take place in the nick- el(II)hexacyanoferrate(II) gelatin-immobilized matrix (GIM) in contact with an aqueous solution of the corresponding ligand. Under the conditions specified, in the NiII-8-mercaptoquinoline, NiII-5-chloro-8-mer captoquinoline,NiII-5-bromo-8-mercaptoquinoline, NiII-5-phenyl-8-mercaptoquinoline and NiII-5-thiomethyl-8-mercaptoquinoline systems, one water-insoluble complex of NiB2 composition (B− is a singly deprotonated ligand) is formed. In the NiII-5,8-dimercaptoquinoline system, two insoluble complexes, monomeric Ni(HB)2 and polymeric [Ni2B2(H2O)2]n (HB− is the singly, and B2− the doubly deprotonated form of the ligands) are generated. Upon complexing in solution or the solid phase, the formation of only one complex is observed in each of systems cited.

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References

  1. Yu. A. Bankovsky, Chemistry of Inner-complex compounds of 8-mercaptoquinoline and its derivatives. Riga, Zinatne, 1978 (Rus.).

  2. O. V. Mikhailov, J. Imaging Sci. Technol., 38, 158 (1994).

    Google Scholar 

  3. O. V. Mikhailov, Transition Met. Chem., 21, 363 (1996).

    Article  Google Scholar 

  4. O. V. Mikhailov, Transition Met. Chem., 22, 000 (1997).

    Google Scholar 

  5. O. V. Mikhailov and V. K. Polovnyak, J. Imaging Sci., 35, 258 (1991).

    Google Scholar 

  6. O. V. Mikhailov, Russ J. Coord. Chem., 18, 1008 (1992).

    Google Scholar 

  7. O. V. Mikhailov, Indian J. Chem., 30A, 252 (1991).

    Google Scholar 

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Authors and Affiliations

  1. Kazan State Technological University, K, Marx Street 68, 420015, Kazan, Russia

    Oleg V. Mikhailov & Marina A. Kazymova

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  1. Oleg V. Mikhailov
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  2. Marina A. Kazymova
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Mikhailov, O.V., Kazymova, M.A. Complexing of nickel(II) with 8-mercaptoquinoline and of its 5-derivatives in nickel(II)hexacyanoferrate(II) gelatin-immobilized matrix systems. Transition Metal Chemistry 24, 350–354 (1999). https://doi.org/10.1023/A:1006948526862

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  • DOI: https://doi.org/10.1023/A:1006948526862

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