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Heterocyclic nickel(II) dithiocarbamates with aromatic thiols as bridging ligands

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Abstract

Binuclear NiII dithiocarbamates, with aromatic monothiols as bridging ligands, of composition [Ni(μ-L) (Rdtc)]2 [dtc = S2CN, R = C4H8O (morph), C5H10 (pip), C4H8 (pld); HL = thiophenol, 4-methylthiophenol or 2-thionaphthol] and [Ni(μ-L)(HR1dtc)]2 {R1 = C11H11N2O (aap)} have been prepared and characterized by elemental analyses, i.r. and electron spectroscopy, magnetochemical and conductivity measurements, and thermal analysis. The methods used indicate that the complexes are diamagnetic, complex non-electrolytes with two square-planar NiS4 chromophores.

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Authors and Affiliations

  1. Department of Inorganic and Physical Chemistry, Palacky University, CZ-771 47, Olomouc, Czech Republic

    Richard Pastorek, Zdeněk Trávníček, Zdeněk šindelář & František Březina

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  1. Richard Pastorek
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  2. Zdeněk Trávníček
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  3. Zdeněk šindelář
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  4. František Březina
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Pastorek, R., Trávníček, Z., šindelář, Z. et al. Heterocyclic nickel(II) dithiocarbamates with aromatic thiols as bridging ligands. Transition Metal Chemistry 24, 304–305 (1999). https://doi.org/10.1023/A:1006948208861

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