Abstract
Investigation of the aqueous coordination chemistry for citrate and vanadium(V) resulted in the isolation and characterization of a dinuclear vanadium(V) citrato complex (1) Na2K2[VO2(Hcit)]2 · 9H2O. Complex (1) is an intermediate between the fully deprotonated and diprotonated citrate vanadate. It may represent an early mobilized precursor in the biosynthesis of FeV-co, as well as a relevant model in the proton transport relay process between P-cluster pair to M-cluster pair. The complex has been characterized by elemental analyses and i.r. spectroscopy. Its i.r. spectra are consistent with a oxo-bridged dinuclear structure as revealed by a single crystal X-ray diffraction study.
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P.W. Ludden, V.K. Shah, G.P. Roberts, M. Homer, R. Allen, T. Paustian, J. Roll, R. Chatterjee, M. Madden and J. Allen, Molybdenum Enzymes, Cofactors and Model Systems, American Chemical Society, Washington DC, 1993, p. 196.
E.M. Page and S.A. Wass, Coord. Chem. Rev., 164, 203 (1997).
B.J. Hales, Adv. Inorg. Biochem., 165 (1990).
K.R. Tsai and H.L. Wan, J. Clust. Sci., 6, 485 (1995).
A. Butler and C.J. Carrano, Coord. Chem. Rev., 109, 61 (1991).
B.M. Nikolova and G.St. Nikolov, J. Inorg. Nucl. Chem., 29, 1013 (1967).
R.H. Dunhill and T.D. Smith, J. Chem. Soc. A, 2189 (1968).
Yu.K. Tselinskii, L.V. Shevcheko and I.I. Kusel'man, Ukr. Khim. Zh., 46, 656 (1980).
P.M. Ehde, I. Anderson and L. Pettersson, Acta Chem. Scand., 143, 136 (1989).
S.G. Vul'fson, A.N. Glebov, O. Yu. Tarasov and Yu. I. Sal'nikov, Dokl. Akad. Nauk. SSSR, 314, 386 (1990).
S.P. Arya and P.K. Sharma, J. Indian Chem. Soc., 69, 793 (1992).
T.A. Dyachkova, R.S. Safin, A.N. Glebov and G.K. Budnikov, Zh. Neorg. Khim., 38, 482 (1993).
T. Kiss, P. Buglyo, D. Sanna, G. Micera, P. Decock and D. Dewaele, Inorg. Chim. Acta, 239, 145 (1995).
S. Burojevic, I. Shweky, A. Bino, D.A. Summers and R.C. Thompson, Inorg. Chim. Acta, 251, 75 (1996).
Z.H. Zhou, H.L. Wan, S.Z. Hu and K.R. Tsai, Inorg. Chim. Acta, 237, 193 (1995).
V. Murugesan, V. Babu, S. Sankaran, Inorg. Chem., 37, 1336 (1998).
G.I. Fillin and V.N. Markin, Deposited Doc. VINITI 3475-3479, 162 (1975); Chem. Abstr., 88, 57252e (1976).
C. Djordjevic, M. Lee and E. Sinn, Inorg. Chem., 28, 719 (1989).
D.W. Wright, P.A. Humiston, W.H. Orme-Johnson and W.H. Davis, Inorg. Chem., 34, 4194 (1995).
Z.H. Zhou, W.B. Yan, H.L. Wan, K.R. Tsai, J.Z. Wang and S.Z. Hu, J. Chem. Crystallogr., 25, 807 (1995).
D.W. Wright, R.T. Chang, S.K. Mandal, W.H. Armstrong, W.H.Z.H. Zhou, H.L. Wan and K.R. Tsai, Chinese Sci. Bull., 40, 749 (1995).
J.D. Pedrosa de Jesus, M. de D. Farropas, P. O'Brien, R.D. Gillard and P.A. Williams, Transition Met. Chem., 8, 193 (1983).
L.R. Assunbeni, M.L. Niven, J.J. Cruywagen and J.B. B Heyns, J. Crystallogr. Spectrosc. Res., 17, 373 (1987).
N.W. Alcock, M. Dudek, R. Grybos, E. Hodorowicz, A. Kanas and A. Samotus, J. Chem. Soc., Dalton Trans., 707 (1990).
M.A. Porai-Koshits, L.A. Aslanov, G.V. Ivanova and T.V. Polynova, J. Struct. Chem. (Engl. Transl.), 9, 401 (1968).
J.E. Berg, S. Brandánge, L. Lindblom and P.E. Werner, Acta. Chem. Scand. Ser. A., 31, 325 (1977).
Z.H. Zhou, W.B. Yan, H.L. Wan and K.R. Tsai, Chin. J. Struc. Chem., 14, 255 (1995).
J. Kim and D.C. Rees, Biochem., 33, 389 (1994).
E.L. Muetterties and L.J. Guggenberger, J. Am. Chem. Soc., 96, 1748 (1974).
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Zhou, ZH., Zhang, H., Jiang, YQ. et al. Complexation between vanadium(V) and citrate: spectroscopic and structural characterization of a dinuclear vanadium(V) complex. Transition Metal Chemistry 24, 605–609 (1999). https://doi.org/10.1023/A:1006947218366
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DOI: https://doi.org/10.1023/A:1006947218366