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Electrophilic behaviour of nitrosyl bound to osmium complexes of 2-(arylazo)pyridine: diazotization of aromatic primary amines

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Abstract

Diazotization of aromatic primary amines with the nitrosyl group derived from [OsX(NO)L2](ClO4)2, L= 2-(m-tolylazo)pyridine; X=Cl (1a), X=NO2 (1b) is described. The reaction sequence was followed by isolating the products at various stages; the products were characterized by physicochemical and spectroscopic methods.

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Authors and Affiliations

  1. Department of Chemistry, The University of Burdwan, Burdwan West Bengal, India

    Sutapa Sinha, Achintya Kumar Banerjee & Barindra Kumar Ghosh

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  1. Sutapa Sinha
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  2. Achintya Kumar Banerjee
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  3. Barindra Kumar Ghosh
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Sinha, S., Banerjee, A.K. & Ghosh, B.K. Electrophilic behaviour of nitrosyl bound to osmium complexes of 2-(arylazo)pyridine: diazotization of aromatic primary amines. Transition Metal Chemistry 23, 151–154 (1998). https://doi.org/10.1023/A:1006947110297

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