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Synthesis of novel coordination compounds of substituted guanidinopyrimidines with ruthenium

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Abstract

The synthesis, characterization, and mechanistic investigation of the coordination compounds of ruthenium with aminoguanidino- substituted ligands are described. These compounds usually possess octahedral, six-coordinate geometry as opposed to the square planar arrangement of the ligand of dicarboxylatoplatinum(II) “carboplatin” or cis-diamminodichloroplatinum(II) – “cis-platin”. The electronic and i.r. absorption spectra of these new chelates are discussed.

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Zawadzki, H., Penkowski, M., Zawadzka, M. et al. Synthesis of novel coordination compounds of substituted guanidinopyrimidines with ruthenium. Transition Metal Chemistry 24, 287–293 (1999). https://doi.org/10.1023/A:1006928924655

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