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Xanthate complexes of nickel with nitrogen donor ligands. Part V

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Abstract

Nickel(II) xanthate complexes of general formula, [Ni(Rxa)2(L)] [R = i-Pr, i-Am, xa = OCS− 2, L = 4,7-diphenyl-1,10-phenanthroline(baphen), 4,4′-dimethyl-2,2′-bipyridyl (me2bpy), 2-9-dimethyl-1,10-phenanthroline(neo) or trans-1,2-diaminocyclohexane (dch)] and [Ni(Rxa)(cyclam)](Rxa) (= 1,4,8,11-tetraazacyclotetradecane) have been synthesized and characterized by elemental analyses, i.r. and electronic spectroscopy, magnetic and conductivity measurements. The complexes with cyclam were studied by cyclic voltammetry. Values of magnetic moments at room temperature lie within the 3.25–3.51 B.M. range and thus indicate the presence of two unpaired electrons, except for the complexes with cyclam, where the anomalous values of 1.76 and 1.74 B.M. were obtained in respect to the nickel(II) complexes. Magnetic susceptibility data for [Ni(i-Prxa)(cyclam)](i-Prxa) were measured over the 79–298 K range and indicate no exchange interaction between paramagnetic nickel(II) centres.

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References

  1. K.K. Nanda, R. Das, L.K. Thompson, K. Venkatsubramanian and Nag K, Inorg. Chem., 33, 1177 (1994).

    Google Scholar 

  2. E. Huyett, M. Carepo, A. Pamplona, R. Franco, I. Moura, J.J.G. Moura and B.M. Ho€man, J. Am. Chem. Soc., 119, 9291 (1997).

    Google Scholar 

  3. E.P. Day, J. Peterson, M.S. Sendova, M.J. Todd and R.P. Hausinger, Inorg. Chem., 32, 634 (1993).

    Google Scholar 

  4. P.A. Clark and D.E. Wilcox, Inorg. Chem., 28, 1326 (1989).

  5. D.L. Tennent and D.R. McMillin, J. Am. Chem. Soc., 101, 2307 (1979).

    Google Scholar 

  6. H.R. Engeseth, D.R. McMillin and E.L. Ulrich, Inorg. Chim. Acta., 67, 145 (1982).

    Google Scholar 

  7. R.J. Haines and A. McAuley, Coord. Chem. Rev., 39, 71 (1981).

    Google Scholar 

  8. A.B.P. Lever, Inorganic Electronic Spectroscopy (2nd ed.). Elsevier Science Publishing Company Inc., New York, 1985.

    Google Scholar 

  9. N.F. Curtis, Coord. Chem. Rev., 3, 3 (1968).

    Google Scholar 

  10. G.M. Shedri, Siemens SHELXTL-PC program package, Siemens Analytical X-Ray Instruments Inc., Madison, WI, 1990.

  11. W.J. Geary, Coord. Chem. Rev., 7, 81 (1981).

    Google Scholar 

  12. L. Sacconi, J. Chem. Soc. (A), 248 (1970).

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Authors and Affiliations

  1. Department of Inorganic and Physical Chemistry, Palacký University, Křížkovského 10, CZ-77147, Olomouc, Czech Republic

    Zdeněk Trávníček, Jan Walla, Libor Kvítek, Zdeněk Šindelář & Martin Biler

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  1. Zdeněk Trávníček
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  2. Jan Walla
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  3. Libor Kvítek
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  4. Zdeněk Šindelář
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  5. Martin Biler
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Trávníček, Z., Walla, J., Kvítek, L. et al. Xanthate complexes of nickel with nitrogen donor ligands. Part V. Transition Metal Chemistry 24, 633–637 (1999). https://doi.org/10.1023/A:1006923722773

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