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On the Behavior of [Zn(Propyltetrazole)6](BF4)2 Single Crystal Under High-Vacuum Conditions

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Abstract

We studied the long-term (190 hours) behaviour of [Zn(propyltetrazole)6](BF4)2 single crystal under high-vacuum (HV) conditions (10−8 torr) with a depth-sensitive technique of positron annihilation spectroscopy (PAS). The obtained data indicate the slow formation of a new near-surface structure which is formed by the decomposition of the [Zn(propyltetrazole)6]2+ ions. The assumption of such a decomposition process was confirmed by additional mass spectroscopic measurements.

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References

  1. P. L. Franke, J. G. Haasnut, A. P. Zuur, Inorg. Chim. Acta, 59 (1982) 5.

    Google Scholar 

  2. P. GÜtlich, A. Hauser, H. Spiering, Angew. Chem. Int. Ed. Engl., 33 (1994) 2024.

    Google Scholar 

  3. M. Bokor, T. Marek, K. Tompa, J. Magn. Res., A122 (1996) 157.

    Google Scholar 

  4. A. VÉrtes, K. SÜvegh, R. Hinek, P. GÜtlich, J. Phys. Chem. Solids, 55 (1994) 1269.

    Google Scholar 

  5. P. J. Schultz, K. G. Lynn, Rev. Mod. Phys., 60 (1988.) 701, and references therein.

    Google Scholar 

  6. T. Marek, Cs. Szeles, Ė. Kiss, A. VÉrtes, K. G. Lynn, Mater. Sci. For., 255–257 (1997) 686.

    Google Scholar 

  7. P. L. Franke, W. L. Groeneveld, Trans. Met. Chem., 6 (1981) 54.

    Google Scholar 

  8. P. Poganiuch, S. Decurtins, P. GÜtlich, J. Am. Chem. Soc., 112 (1990) 3270.

    Google Scholar 

  9. K. G. Lynn, H. Lutz, Phys. Rev., B22 (1980) 4143.

    Google Scholar 

  10. K. G. Lynn, B. Nielsen, J. H. Quateman, Appl. Phys. Lett., 47 (1985) No. 3, 239.

    Google Scholar 

  11. A. van Veen, H. Schut, J. de Vries, R. A. Hakvoort, M. R. Ijpma, in: Slow Positron Beams for Solids and Surfaces, P. J. Schultz, G. R. Massoumi, P. J. Simpson (Eds), Am. Inst. of Phys., New York, 1990, p. 171.

  12. V. J. Ghosh, Appl. Surf. Sci., 85 (1995) 187.

    Google Scholar 

  13. Y. Nagai, H. Saito, T. Hyodo, A. VÉrtes, K. SÜvegh, Phys. Rev., B57 (1998) 14119.

    Google Scholar 

  14. M. Bokor, T. Marek, K. SÜvegh, I. Konkoly Thege, A. VÉrtes, J. Radioanal. Nucl. Chem., 200 (1995) 265.

    Google Scholar 

  15. M. Bokor, T. Marek, K. SÜvegh, Zs. BÖcskey, J. Buschmann, A. VÉrtes, Acta Phys. Polonica, A95 (1999) 469.

    Google Scholar 

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Authors and Affiliations

  1. Department of Nuclear Chemistry, Eötvös Loránd University, P.O.Box 32, H-1518, Budapest, Hungary

    T. Marek

  2. Department of General and Inorganic Chemistry, Eötvös Loránd University, P.O.Box 32, H-1518, Budapest, Hungary

    T. Marek, G. Molnár & J. Borossay

  3. Department of Nuclear Chemistry, Eötvös Loránd University, P.O. Box 32, H-1518, Budapest, Hungary

    Cs. Szeles & A. Vértes

  4. Departments of Material Science and Physics, Brookhaven National Laboratory, Upton, NY, USA

    Cs. Szeles & K. G. Lynn

Authors
  1. T. Marek
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  2. Cs. Szeles
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  3. G. Molnár
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  4. J. Borossay
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  5. A. Vértes
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  6. K. G. Lynn
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Marek, T., Szeles, C., Molnár, G. et al. On the Behavior of [Zn(Propyltetrazole)6](BF4)2 Single Crystal Under High-Vacuum Conditions. Journal of Radioanalytical and Nuclear Chemistry 245, 329–335 (2000). https://doi.org/10.1023/A:1006762505559

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