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Influence of Continental Sources on Oceanic Air Composition at the Eastern Edge of the North Atlantic Ocean, TOR 1992–1995

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Abstract

The atmospheric concentrations of O3, NMHCs, PAN and NOx were measured at the TOR station in Porspoder (Brittany, France) from 1992 to 1995. The results from April 1992 to December 1994 are reported here. In order to study the behaviour of trace gases in the air masses coming from the Atlantic Ocean, the origin of these air masses was characterised by the analysis of the five-day back-trajectories reaching 950 mbar at Porspoder. Three kinds of oceanic air masses are considered, depending on their origin: North Atlantic northern and southern latitudes and North American continent. It appears that the oceanic high-latitude troposphere was strongly influenced by continental emissions, which in turn impacted the median latitude troposphere during polar outflow events. A greater accumulation of anthropogenic compounds in the Arctic sector was calculated and may be at the origin of the high oxidant levels measured in spring in this same sector. The influence of north American emissions on the European coast was also studied and seems to reach a maximum in spring. Long-range transport of long- lived species was observed throughout the year, but evidence for winter transport of more reactive species, such as ethene, is also shown. Meteorological parameters and local photochemistry appear to play an important role in the distribution of the pollutants over the North Atlantic Ocean throughout the year. Further investigations are needed to give more complete information about the origin, formation and destruction of the secondary pollutants.

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References

  • Anderson, B. E., Gregory, G. L., Barrick, J. D. W. Jr., J. E. C., Sachse, G. W., Shipman, M. C., and Hudgins, C. H., 1994: Summertime tropospheric ozone distributions over central and eastern Canada, J. Geophys. Res. 99(D1), 1781–1792.

    Google Scholar 

  • Anfossi, D., Sandroni, S., and Viarenzo, S., 1991: Tropospheric ozone in the nineteenth century: The Moncalieri series, J. Geophys. Res. 96, 17349–17352.

    Google Scholar 

  • Atherton, C. S., Grotch, S., Parrish, D. D., Penner, J. E., and Walton, J. D., 1996: The role of anthropogenic emissions of NOx on tropospheric ozone over the North Atlantic Ocean: A three-dimensional, global model study, Atmos. Environ. 30(10/11), 1739–1749.

    Google Scholar 

  • Bazhanov, V., 1992: Modern Investigations of Atmospheric Ozone over the Ocean, Hydrometeorology publishers, Moscow.

    Google Scholar 

  • Beine, H. J., Jaffe, D. A., Blake, D. R., Atlas, E., and Harris, J., 1996: Measurements of PAN, alkyl nitrates, and halocarbons during spring in interior Alaska, J. Geophys. Res. 101(D7), 12613–12619.

    Google Scholar 

  • Berkowitz, C. M., Busness, K. M., Chapman, E. G., and Thorp, J. M., 1995: Observations of depleted ozone within the boundary layer of the western north Atlantic, J. Geophys. Res. 100(D6), 11483–11496.

    Google Scholar 

  • Blake, D. R. and Rowland, S., 1986: Global atmospheric concentrations and source strength of ethane, Nature 321, 231–233.

    Google Scholar 

  • Borrel, P., Borrel, P. M., and Seiler, W., 1990: Transport and transformation of pollutants in the troposphere — Proceedings of Eurotrac Symposium '90 — 2nd–5th April, 1990, SPB Academic Publishing bv, Garmisch-Partenkirchen, Federal Republic of Germany, p. 586.

  • Bottenheim, J. W. and Shepherd, M. F., 1995: C2–C6 hydrocarbon measurements at four rural locations across Canada, Atmos. Environ. 29(6), 647–664.

    Google Scholar 

  • Davis, D. D., Crawford, J., Cheng, G., Chameides, W., Liu, S., Bradshaw, J., Sandholm, S., Sasche, G., Gregory, G., Anderson, B., Bachmeier, A., Collins, J., Browell, E., Blake, D., Rowland, S., Kondo, Y., Singh, H., Talbot, R., Heikes, B., Merril, J., Rodriguez, J., and Newell, R. E., 1996: Assessment of ozone photochemistry in the western North Pacific as inferred from PEM-West A observations during the fall 1991, J. Geophys. Res. 101(D1), 2111–2134.

    Google Scholar 

  • Derwent, R. G., Simmonds, P. G., and Collins, W. J., 1994: Ozone and carbon monoxide measurements at a remote maritime location, Mace Head, Ireland, from 1990 to 1992, Atmos. Environ. 28(16), 2623–2637.

    Google Scholar 

  • EUROTRAC, 1994: The TOR Network — A Description of TOR Measurement Stations, Garmisch-Partenkirchen, p. 182.

  • Fehsenfeld, F. C., Daum, P., Leaitch, W. R., Trainer, M., Parrish, D. D., and Hübler, G., 1996: Transport and processing of O3 and O3 precursors over the North Atlantic: An overview of the 1993 North Atlantic Regional Experiment (NARE) summer intensive, J. Geophys. Res. 101(D22), 28877–28891.

    Google Scholar 

  • Fenneteaux, I., 1998: Etude de l'évolution des composés atmosphériques en trace (HCNM, O3, PAN, NOx) dans la couche limite, à la frontière océan Atlantique-continent européen, Université Paris 12 — Val-de-Marne, Créteil, France.

    Google Scholar 

  • Gallagher, M. S., Carsey, T. P., and Farmer, M. L., 1990: Peroxyacetyl nitrate in the North Atlantic marine boundary layer, Global Biogeochem. Cycles 4(3), 297–308.

    Google Scholar 

  • Harris, R. C., Wofsy, S. C., Bartlett, D. S., Shipham, M. C., Jacob, D. J. Jr., J. M. H., Bendura, R. J., Drewry, J. W., McNeal, R. J., Navarro, R. L., Gidge, R. N., and Rabine, V. E., 1992: The Arctic Boundary Layer Expedition (ABLE 3A): July–August 1988, J. Geophys. Res. 97(D15), 16,383–16,394.

    Google Scholar 

  • Honrath, R. E., Hamlin, A. J., and Merrill, J. T., 1996: Transport of ozone precursors from the Arctic troposphere to the North Atlantic region, J. Geophys. Res. 101(D22), 29335–29351.

    Google Scholar 

  • Hough, A. M., 1991: Development of a 2 dimensional global tropospheric model: Model chemistry, J. Geophys. Res. 96(D4), 7325–7362.

    Google Scholar 

  • Jacob, D. J., Wofsy, S. C., Backwin, P. S., Fan, S.-M., Harriss, R. C., Talbot, R. W., Bradshaw, J. D., Sandholm, S. T., Singh, H. B., Browell, E. V., Gregory, G. L., Sachse, G. W., Shipham, M. C., Blake, D. R., and Fitzjarrald, D. R., 1992: Summertime photochemistry of the troposphere at high northern latitudes, J. Geophys. Res. 97(D15), 16421–16431.

    Google Scholar 

  • Jobson, B. T., Niki, H., Yokouchi, Y., Bottenheim, J., Hopper, F., and Leaitch, R., 1994a: Measurements of C2–C6 hydrocarbons during the Polar Sunrise 1992 Experiment: Evidence for Cl atom and Br atom chemistry, J. Geophys. Res. 99(D12), 25355–25368.

    Google Scholar 

  • Jobson, B. T., Wu, Z., Niki, H., and Barrie, L. A., 1994b: Seasonal trends of isoprene, C2–C5 alkanes, and acetylene at a remote boreal site in Canada, J. Geophys. Res. 99(D1), 1589–1599.

    Google Scholar 

  • Kasibhatla, P., II, H. L., Klonecki, A., and Chameides, W. L., 1996: Three-dimensional view of the large-scale tropospheric ozone distribution over the North Atlantic Ocean during summer, J. Geophys. Res. 101(D22), 29305–29316.

    Google Scholar 

  • Kleinman, L. I., Daum, P. H., Springston, S. R., Leaitch, W. R., Banic, C. M., Isaac, G. A., Jobson, B. T., and Niki, H., 1996: Measurement of O3 and related compounds over southern Nova Scotia: 2. Photochemical age and vertical transport, J. Geophys. Res. 101(D22), 29061–29074.

    Google Scholar 

  • Koppmann, R., Bauer, R., Johnen, F. J., Plass, C., and Rudolph, J., 1992: The distribution of light nonmethane hydrocarbons over the mid-Atlantic: Results of the Polarstern Cruise ANT VII/1, J. Atmos. Chem. 15(3–4), 215–234.

    Google Scholar 

  • Liu, S. C., Trainer, M., Fehsenfeld, F. C., Parrish, D. D., Williams, E. J., Fahey, D. W., Huber, G., and Murphy, P. C., 1987: Ozone production in the rural troposphere and implications for regional and global ozone distributions, J. Geophys. Res. 92, 4191–4207.

    Google Scholar 

  • Luria, M. and Meagher, J. F., 1988: Computer simulation of the boundary layer and removal of atmospheric pollutants over the western Atlantic ocean, Atmos. Environ. 22(2), 307–316.

    Google Scholar 

  • Marenco, A., Gouget, H., Nedelec, P., Pages, J. P., and Karcher, F., 1994: Evidence of a long-term increase in tropospheric ozone from Pic du Midi data series: Consequences: Positive radiative forcing, J. Geophys. Res. 99, 16617–16632.

    Google Scholar 

  • Merril, J., Bleck, R., and Avila, L., 1985: Modeling atmospheric transport to the Marshall Islands, J. Geophys. Res. 90(D12), 12927–12936.

    Google Scholar 

  • Merril, J. T., Moody, J. L., Oltmans, S. J., and II, H. L., 1996: Meteorological analysis of tropospheric ozone profiles at Bermuda, J. Geophys. Res. 101(D22), 29201–29211.

    Google Scholar 

  • Moxim, W. J., II, H. L., and Kasibhatla, P. S., 1996: Simulated global tropospheric PAN: Its transport and impact on NOx, J. Geophys. Res. 101(D7), 12621–12638.

    Google Scholar 

  • Oltmans, S. J., II, H. L., Harris, J. M., Moody, J. L., Lathrop, J. A., Cuevas, E., Trainer, M., O'Neill, M. S., Prospero, J. M., Vömel, H., and Johnson, B. J., 1996: Summer and spring ozone profiles over the North Atlantic from ozonesonde measurements, J. Geophys. Res. 101(D22), 29179–29200.

    Google Scholar 

  • Oltmans, S. J. and Levy II, H., 1992: Seasonal cycle of surface ozone over the western North Atlantic, Nature 358, 392–394.

    Google Scholar 

  • Parrish, D. D., Hahn, C. J., Williams, E. J., Norton, R. B., and Fehsenfeld, F. C., 1992: Indication of photochemical histories of air masses from measurements of atmospheric trace species at Point Arena, California, J. Geophys. Res. 97(D14), 15883–15901.

    Google Scholar 

  • Penkett, S. A. and Brice, K. A., 1986: The spring maximum in photo-oxidants in the Northern hemisphere, Lett. Nature 319, 655–657.

    Google Scholar 

  • Penkett, S. A., Blake, N. J., Lightman, P., Marsh, A. R. W., Anwyl, P., and Butcher, G., 1993: The seasonal variation of nonmethane hydrocarbons in the free troposphere over the Atlantic Ocean: Possible evidence for extensive reaction of hydrocarbons with the nitrate radical, J. Geophys. Res. 98(D2), 2865–2885.

    Google Scholar 

  • Rudolph, J., 1988: Two-dimensional distribution of light hydrocarbons: Results from the STRATOZ III experiment, J. Geophys. Res. 93(D7), 8367–8377.

    Google Scholar 

  • Rudolph, J. and Johnen, F. J., 1990: Measurements of light atmospheric hydrocarbons over the Atlantic in regions of low biological activity, J. Geophys. Res. 95(D12), 20583–20591.

    Google Scholar 

  • Rudolph, J., 1995: The tropospheric distribution and budget of ethane, J. Geophys. Res. 100(D6), 11369–11381.

    Google Scholar 

  • Singh, H. B., Herlth, D., O'Hara, D., Bradshaw, J. D., Santholm, S. T., Talbot, R., Gregory, G. L., Sachse, G. W., Blake, D. R., and Wofsy, S. C., 1994: Summertime distribution of PAN and other reactive nitrogen species in the northern high-latitude atmosphere of eastern Canada, J. Geophys. Res. 99(D1), 1821–1835.

    Google Scholar 

  • Singh, H. B., O'Hara, D., Herlth, D., Bradshaw, J. D., Sandholm, S. T., Gregory, G. L., Sachse, G. W., Blake, D. R., Crutzen, P. J., and Kanakidou, M. A., 1992: Atmospheric measurements of peroxyacetyl nitrate and other organic nitrates: Possible sources and sinks, J. Geophys. Res. 97(D15, 16511–16522.

    Google Scholar 

  • Singh, H. B. and Zimmerman, P. B., 1992: Atmospheric distribution and sources of nonmethane hydrocarbons, in J. O'Nriagu (ed.), Gaseous Pollutants, Wiley Interscience, pp. 177–235.

  • Sirois, A. and Bottenheim, J. W., 1995: Use of backward trajectories to interpret the 5-year record of PAN and O3 in ambient air concentrations at Kejimkujik National Park, Nova Scotia, J. Geophys. Res. 100(D2), 2867–2881.

    Google Scholar 

  • Winkler, P., 1988: Surface ozone over the Atlantic Ocean, J. Atmos. Chem. 7(3), 73–91.

    Google Scholar 

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Authors and Affiliations

  1. URA 1404 du CNRS, Univ. Paris VII et Paris XII, 61 Av. du General de Gaulle, 94010, Creteil Cedex, France

    I. Fenneteaux, P. Colin, A. Etienne, H. Boudries, A. L. Dutot, P. E. Perros & G. Toupance

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  1. I. Fenneteaux
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  2. P. Colin
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  3. A. Etienne
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  4. H. Boudries
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  5. A. L. Dutot
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  6. P. E. Perros
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  7. G. Toupance
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Fenneteaux, I., Colin, P., Etienne, A. et al. Influence of Continental Sources on Oceanic Air Composition at the Eastern Edge of the North Atlantic Ocean, TOR 1992–1995. Journal of Atmospheric Chemistry 32, 233–280 (1999). https://doi.org/10.1023/A:1006140223711

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