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Doppler Detection of Hydroxyl Column Abundance in the Middle Atmosphere: 2. Measurement for Three Years and Comparison with a 1D Model

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Abstract

The hydroxyl column abundance in the middle atmosphere is measured for 3 years in Tokyo by ground-based uv absorption spectroscopy utilizing the Doppler shift of the solar spectrum due to the solar rotation. The diurnal and seasonal variations of the measured column abundance are found to be reproduced qualitatively by a one-dimensional photochemical-diffusive model; however, the measured column abundances are smaller than the calculated by 20 to 30% systematically.

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References

  • Badger, R. M., Wright, A. C., and Whitlock, R. F., 1965: Absolute intensities of the discrete and continuous absorption bands of oxygen gas at 1.26 and 1.065 µ and the radiative lifetime of the 1Δg state oxygen, J. Chem. Phys. 43, 4345–4350.

    Google Scholar 

  • Brasseur, G. and Simon, P. C., 1981: Stratospheric chemical and thermal response to long-term variability in solar UV irradiance, J. Geophys. Res. 86, 7343–7362.

    Google Scholar 

  • Burnett, C. R., 1976: Terrestrial OH abundance measurement by spectroscopic observation of resonance absorption of sunlight, Geophys. Res. Lett. 3, 319–322.

    Google Scholar 

  • Burnett, C. R. and Burnett, E. B., 1981: Stratospheric measurements of the vertical column abundance of hydroxyl (OH) in the earth's atmosphere, J. Geophys. Res. 86, 5185–5202.

    Google Scholar 

  • Burnett, C. R. and Burnett, E. B., 1982: Vertical column abundance of atmospheric OH at solar maximum from Fritz Peak, Colorado, Geophys. Res. Lett. 9, 708–711.

    Google Scholar 

  • Burnett, C. R. and Burnett, E. B., 1984: Observational results on the vertical column abundance of atmospheric hydroxyl: Description of its seasonal behavior 1977–1982 and of the 1982 El Chichon perturbation, J. Geophys. Res. 89, 9603–9611.

    Google Scholar 

  • Burnett, C. R. and Burnett, E. B., 1985: Atmospheric hydroxyl response to the partial solar eclipse of May 30, 1984, Geophys. Res. Lett. 12, 263–266.

    Google Scholar 

  • Burnett, C. R., Minschwaner, K. R., and Burnett, E. B., 1988: Vertical column abundance measurements of atmospheric hydroxyl from 26°, 40°, and 65° N, J. Geophys. Res. 93, 5241–5253.

    Google Scholar 

  • Burnett, C. R., Minschwaner, K.R., and Burnett, E.B., 1990: OH vertical column abundance: Tropical measurements, J. Geophys. Res. 95, 16491–16495.

    Google Scholar 

  • Burnett, E. B. and Burnett, C. R., 1995: Enhanced production of stratospheric OH from methane oxidation at elevated reactive chlorine levels in northern midlatitudes, J. Atmos. Chem. 21, 13–41.

    Google Scholar 

  • Burnett, C. R. and Burnett, E. B., 1996: The regime of decreased OH vertical column abundance at Fritz Peak Observatory, CO: 1991–1995, Geophys. Res. Lett. 23, 1925–1927.

    Google Scholar 

  • Campbell, I. M. and Gray, C. N., 1973: Rate constant for O(3P) recombination and association with N(4S), Chem. Phys. Lett. 18, 607–609.

    Google Scholar 

  • Carr, E. S., Harwood, R. S., Mote, P. W., Peckam, G. E., Suttie, R. A., Lahoz, W. A., O'Neill, A., Froidevaux, L., Jarno, R. F., Read, W.G., Waters, J.W., Swinbank, R., 1995: Tropical stratospheric water vapor measured by the microwave limb sounder (MLS), Geophys. Res. Lett. 22, 691–694.

    Google Scholar 

  • Chance, K., Traub, W. A., Johnson, D. G., Jucks, K. W., Ciarpallini, P., Stachnik, R. A., Salawitch, R. J., and Michelsen, H. A., 1996: Simultaneous measurements of stratospheric HOx, NOx, and Clx: Comparison with a photochemical model, J. Geophys. Res. 101, 9031–9043.

    Google Scholar 

  • CIRA: 1986, 1990, COSPAR International Reference Atmosphere 1986, (D. Rees, J. J. Barnett and K. Labitzke (eds)), 1990, Adv. Space Res. 10(12), 336–339.

  • Clancy, R. T., Sandor, B. J., Rusch, D.W., and Muhleman, D. O., 1994: Microwave observations and modeling of O3, H2O and HO2 in the mesosphere, J. Geophys. Res. 99, 5465–5473.

    Google Scholar 

  • Cohen, R. C., Wennberg, P. O., Stimpfle, R. M., Koplow, J., Anderson, J. G., Fahey, D. W., Woodbridge, E. I., Keim, E. R., Gao, R., Proffitt, M. H., Loewenstein, M., and Chan, K. R., 1994: Are models of catalytic removal of O3 by HOx accurate? Constraints from in situ measurements of the OH to HO2 ratio, Geophys. Res. Lett. 21, 2539–2542.

    Google Scholar 

  • Conway, R. R., Stevens, M. H., Cardon, J. G., Zasadil, S. E., Brown, C. M., Morrill, J. S., and Mount, G. H., 1996: Satellite measurements of hydroxyl in the mesosphere, Geophys. Res. Lett. 23, 2093–2096.

    Google Scholar 

  • DeMore, W. B., Sander, S. P., Golden, D. M., Hampson, R. F., Kurylo, M. J., Howerd, C. J., Ravishankara, A. R., Kolb, C. E., and Molina, M. J., 1994: Chemical kinetics and photochemical data for use in stratospheric modeling, JPL Publ. 9426.

  • Donahue, N.M., Dubey, M. K., Mohrschladt, R., Demerjian, K. L., and Anderson, J. G., 1997: High-pressure flow of the reactions OH + NOx → HONOx: Errors in the falloff region, J. Geophys. Res. 102, 6159–6168.

    Google Scholar 

  • Froidevaux, L., Allen, M., and Yung, Y. L., 1985: A critical analysis of ClO and O3 in the midlatitude stratosphere, J. Geophys. Res. 90, 12999–13029.

    Google Scholar 

  • Gordley, L. L., Russel III, J. M., Mickley, L. J., Frederick, J. E., Park, J. H., Stone, K. A., Beaver, G. M., McInerney, J. M., Deaver, L. E., Toon, G. C., Murcray, F. J., Blatherwick, D., Gunson, M. R., Abbatt, J. P. D., Mauldin III, R. L., Mount, G.H., Sen, B. and Blavier, J.-F., 1996: Validation of nitric oxide and nitrogen dioxide measurements made by the halogen occultation experiment for UARS platform, J. Geophys. Res. 101, 10241–10266.

    Google Scholar 

  • Iwagami, N., Inomata, S., Murata, I., and Ogawa, T., 1995: Doppler detection of hydroxyl column abundance in the middle atmosphere, J. Atmos. Chem. 20, 1–15.

    Google Scholar 

  • Kumer, J. B., Mergenthaler, J. L., Roche, A. E., Nightingale, R.W., Ely, G. A., Uplinger, W. G., Gille, J. C., Massie, S. T., Bailey, P. L., Gunson, M. R., Abrams, M. C., Toon, G. C., Sen, B., Blavier, J.F., Stachnik, R. A., Webster, C. R., May, R. D., Murcray, D. G., Murcray, F. J., Goldman, A., Traub, W. A., Jucks, K.W., and Johnson, D. G., 1996: Comparison of correlative data with HNO3 version 7 from the CLAES instrument deployed on the NASA Upper Atmosphere Research Satellite, J. Geophys. Res. 101, 9621–9656.

    Google Scholar 

  • Lean, J., 1987: Solar ultraviolet irradiance variations: A review, J. Geophys. Res. 92, 839–868.

    Google Scholar 

  • McCormick, M. P., Chiou, E.W., McMaster, L. R., Chu, W. P., Larsen, J. C., Rind, D., and Oltmans, S., 1993: Annual variations of water vapor in the stratosphere and upper troposphere observed by Stratospheric Aerosol and Gas Experiment II, J. Geophys. Res. 98, 4867–4874.

    Google Scholar 

  • Michelsen, H. A., Salawitch, R. J., Wennberg, P. O., and Anderson, J. G., 1994: Production of O(1D) from photolysis of O3, Geophys. Res. Lett. 21, 2227–2230.

    Google Scholar 

  • Morgan, M. F., Torr, D. G., and Torr, M. R., 1993: Preliminary measurements of mesospheric OH X 2Π by ISO on ATLAS 1, Geophys. Res. Lett. 20, 511–514.

    Google Scholar 

  • Nedoluha, G. E., Bevilacqua, R. M., Gomez, R. M., Waltman, W. B., Thacker, D. L., and Matthews, W. A., 1996: Measurements of water vapor in the middle atmosphere and implications for mesospheric transport, J. Geophys. Res. 101, 21183–21193.

    Google Scholar 

  • Nicolet, P., 1979: Photodissociation of nitric oxide in the mesosphere and stratosphere: Simplified numerical relations for atmospheric model calculations, Geophys. Res. Lett. 6, 866–868.

    Google Scholar 

  • Nicolet, P., 1981a: The solar spectral irradiance and its action in the atmospheric photodissociation processes, Planet. Space Sci. 29, 951–974.

    Google Scholar 

  • Nicolet, P., 1981b: The photodissociation of water vapor in the mesosphere, J. Geophys Res. 86, 5203–5208.

    Google Scholar 

  • Ogawa, T. and Shimazaki, T., 1975: Diurnal variations of odd nitrogen and ionic densities in the mesosphere and lower thermosphere: Simultaneous solution of photochemical-diffusive equations, J. Geophys Res. 80, 3945–3960.

    Google Scholar 

  • Pickett, H. M. and Peterson, D. B., 1996: Comparison of measured stratospheric OH with prediction, J. Geophys. Res. 101, 16789–16796.

    Google Scholar 

  • Remsberg, E. E., Russell III, J.M., and Wu, C.Y., 1990: An interim reference model for the variability of the middle atmosphere water vapor distribution, Adv. Space Res. 10(6), 51–64.

    Google Scholar 

  • Shimazaki, T. and Ogawa, T., 1974: A theoretical model of minor constituent distributions in the stratosphere including diurnal variations, J. Geophys. Res. 79, 3411–3423.

    Google Scholar 

  • Shimazaki, T., 1985: Minor Constituents in the Middle Atmosphere, Terra Sci. Publ. Co., Tokyo, D. Reidel Publ. Co., Dordrecht.

    Google Scholar 

  • Siskind, D. E., Connor, B. J., Eckman, R. S., Remsberg, E. E., Tsou, J. J., and Parrish, A., 1995: An intercomparison of model ozone deficits in the upper stratosphere and mesosphere from two data sets, J. Geophys. Res. 100, 11191–11201.

    Google Scholar 

  • Summers, M. E., Conway, R. R., Siskind, D. E., Bevilacqua, R., Strobel, D. F., and Zasadil, S., 1996: Mesospheric HOx photochemistry: Constraints from recent satellite measurements of OH and H2O, Geophys. Res. Lett. 23, 2097–2100.

    Google Scholar 

  • Toohey, D.W., Avallone, L.M., Allen, N. T., Demusz, J. N., Hazen, J. N., and Anderson, J. G., 1993: The performance of a new instrument for in situ measurements of ClO in the lower stratosphere, Geophys. Res. Lett. 20, 1791–1794.

    Google Scholar 

  • Tuck, A. F., Russell III, J.M., and Harries, J. E., 1993: Stratospheric dryness: Antiphased desiccation over Micronesia and Antarctica, Geophys. Res. Lett. 20, 1227–1230.

    Google Scholar 

  • U.S. Standard Atmosphere, 1966: U.S. Government Printing Office, Washington, D.C.

  • Waters, J. W., Froidevaux, L., Read, W. G., Manney, G. L., Elson, L. S., Flower, D. A., Jarnot, R. F., and Harwood, R. S., 1993: Stratospheric ClO and ozone from the microwave limb sounder on the upper atmosphere research satellite, Nature 362, 597–602.

    Google Scholar 

  • Wood, S.W., Keep, D. J., Burnett, C. R., and Burnett, E. B., 1994: Column abundance measurements of atmospheric hydroxyl at 45° S, Geophys. Res. Lett. 21, 1607–1610.

    Google Scholar 

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Iwagami, N., Inomata, S. & Ogawa, T. Doppler Detection of Hydroxyl Column Abundance in the Middle Atmosphere: 2. Measurement for Three Years and Comparison with a 1D Model. Journal of Atmospheric Chemistry 29, 195–216 (1998). https://doi.org/10.1023/A:1005928612004

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