Abstract
Indraprastha Power Station (IPP Stn) and Rajghat Power House (RPH), owned by Delhi Electric Supply Undertaking, are both coal-fired power stations located on Ring Road in New Delhi. Ash content of the coal used ranges between 38–47%. The ash is collected in electrostatic precipitators which have an efficiency of 99.3% (IPP station), and 99.7% (RPH). There are instances of major dust pollution around the power stations from fly ash dispersal. The main method of disposal of fly ash from the power stations is by mixing with water, the resultant slurry is pumped through pipes to ash disposal ponds. The supernatant from these ponds is discharged into River Yamuna. Field studies have revealed large quantities of fly ash being deposited into the river. Local populations of Eichhornia crassipes have reduced dramatically between 1987–1995, with a marked reduction in the year 1994–1995. Field studies, conducted in January, 1995 have investigated the impact of fly ash dispersal in the Delhi region with particular reference to metal contamination. Elemental concentrations for a range of elements are determined by ICP-AES in fly ash and top soils along four transects from the power stations up to a distance of 8 km. The effects of fly ash leachates from the ash settling ponds on the river are determined by analyzing river overbank soils and vegetation for their elemental contents. It is concluded that fly ash dispersal from the stacks are a source of alkali, alkaline-earth and to some extent heavy metals in soils in the vicinity of the power stations, and enrichment of elements in river overbank soils are a result of discharge of fly ash leachates from ash disposal ponds. However, the impact from both these sources of metal contamination is not large enough to give cause for concern. Marked reduction in populations of Eichhornia crassipes downstream of the river where it receives leachates from the ash disposal ponds are attributed to turbidity of the ash pond leachates and metal toxicity. Elemental enrichment in the floodplain soils, as a result of fly ash particle deposition during monsoons, may enhance the horticultural value of these soils as is shown by a healthy cultivated crop of Brassica juncea.
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Ajmal, M., Khan, M. A. and Nomani, A. A.: 1985, ‘Distribution of heavy metals in plants and fish of the Yamuna river (India)’, Environ. Monit. Assess. 5, 361–367.
Akcin, G., Guldede, N. and Saltabas, O.: 1993, ‘Zinc removal in strongly basic solutions by water hyacinth’, J. Environ. Sci. Health A28, 1727–1735.
Balasooriya, I., Paulraj, P. J., Abeygunewardena, S. I. and Nanayakkara, C.: 1984, ‘The Biology of Water Hyacinth: Physico Chemical Properties of the Water Supporting Eichhornia crassipes (MART.) Solms’, in Thyagarajan, G. (ed.), Proc. Internat. Conf. on the Water Hyacinth, 7–11 February, 1983, UNEP, Nairobi, pp. 318–333.
Berrow, M. L. and Ure, A. M.: 1985, ‘Trace element distribution and mobilization in Scottish soils with particular reference to cobalt, copper and molybdenum’, Environ. Geochem. Health 8, 19–24.
Bowen, H. J. M.: 1979, Environmental Chemistry of the Elements, Academic Press, London.
BSI (British Standards Institution): 1990, British Standard Methods of test for Soils for civil engineering purposes, Part 3, Chemical and electrochemical tests, BS1377:Part3:1990.
CPCB: 1993–1994, Central Pollution Control Board, Pollution Statistics Delhi, Delhi.
CPCB: 1994, Central Pollution Control Board, Annual Report 1993–94, Delhi.
Chigbo, F. E., Smith, R. W. and Shore, F. L.: 1982, ‘Uptake of arsenic, cadmium, lead and mercury from polluted waters by the water hyacinth Eichhornia crassipes’, Environ. Pollut. A27, 31–36.
Coles, D. G., Ragaini, R. C., Ondov, J. M., Fisher, G. L., Silberman, D. and Prentice, B. A.: 1979, ‘Chemical studies of stack fly ash from a coal-fired power plant’, Environ. Sci. Technol. 13, 455–459.
Davison, R. L., Natusch, D. F. S., Wallace, J. R. and Evans, Jr, C. A.: 1974, ‘Trace elements in fly ash: dependence of concentration on particle size’, Environ. Sci. Tech. 8, 1107–1113.
Farago, M. E. and Parsons, P. J.: 1985, ‘The recovery of platinum metals by the water hyacinth’, Environ. Technol. Letters 6, 165–174.
Farago, M. E., Mehra, A. and Banerjee, D. K.: 1989, ‘A preliminary investigation of pollution in the River Yamuna, Delhi, India: metal concentrations in river bank soils and plants’, Environ. Geochem. Health 11, 149–156.
Fulekar, M. H.: 1983, ‘Release and behaviour of selected trace elements in soil-water environment caused by coal-fired power plants fly ash disposal’, PhD Thesis, Jawaharlal Nehru University, New Delhi, India.
Fulekar, M. H. and Dave, J. M.: 1986, ‘Disposal of flyash - An environmental problem’, Intern. J. Environ. Studies 26, 191–215.
Fulekar, M. H. and Dave, J. M.: 1990, ‘Environmental impact assessment of fly ash from coal-fired power plants’, Encology 4, 25–34.
Fulekar, M. H., Naik, D. S. and Dave, J. M.: 1983, ‘Heavy metals in Indian coals and corresponding fly-ash and their relationship with particulate size’, Intern. J. Environ. Studies 9, 139–144.
Haider, Z. S., Malik, K.M. A., Rahman, M.M. and Ali, M. A.: 1984, ‘Pollution Control by the Water Hyacinth’, in Thyagarajan, G. (ed.), Proc. Internat. Conf. on the Water Hyacinth, 7–11 February, 1983, UNEP, Nairobi, pp. 627–634.
Hardy, J. K. and Raber, N. B.: 1985, ‘Zinc uptake by the water hyacinth: effects of solution factors’, Chemosphere 14, 1155–1166.
HSE: 1991, ‘Guidance for classification of contaminated soils’, HMSO, London.
Jamil, K.: 1990, ‘Environmental Biology ofWater Hyacinth’, ASF-Science Series, Vidyanagar, India.
Kaakinen, J. W., Jorden, R. M., Lawsani, M. H. and West, R. E.: 1975, ‘Trace element behaviour in coal-fired power plant’, Environ. Sci. Techn. 9, 862–869.
Kabata-Pendias, A. and Pendias, H.: 1984, Trace Elements in Soils and Plants, CRC Press, Florida.
Khanna, P. R.: 1995, Addl. Chief Engineer, Rajghat Power House, New Delhi. Personal communication.
Klein, D. H., Andren, A. W., Carter, J. A., Emery, J. F., Feldman, C., Fulkerson, W., Lyon, W. S., Ogle, J. C., Talmy, Y., Van Hook, R. I. and Bolton, N.: 1975, ‘Pathways of thirty-seven trace elements through coal-fired power plant’, Environ. Sci. Tech. 9, 973–979.
Klusek, C. S., Miller, K. M. and Heit, M. 1983, ‘Trace element and radionuclide mass balances at a coal-fired electric generating station’, Environment International 9, 139–144.
Minocha, Y. P.: 1995, Superintending Engineer, Indraprastha Power Station, New Delhi. Personal communication.
Misra, U. C., Lalit, B. Y. and Ramachandran, T. V.: 1980, ‘Radioactivity release to the environment by thermal power stations using coal as a fuel’, Sci. Total Environ. 14, 77–88.
Muramoto, S. and Oki, Y.: 1983, ‘Removal of some heavy metals from polluted water by water hyacinth’, Bull. Environ. Contam. Toxicol. 30, 170–177.
Negi, B. S. and Meenakshy, V.: 1991, ‘Characterisation of coal fly ash from thermal power plants in India’, in Sahu, K. C. (ed.), Proc. International Conference on Environmental Impact of Coal Utilization, 1991, Bombay, India, pp. 143–152.
O'Keeffe, D. H., Hardy, J. K. and Rao, R. A.: 1984, ‘Cadmium uptake by the water hyacinth: effects of solution factors’, Environ. Pollut. Ser. A 34, 133–147.
Pacyna, J. M.: 1984, ‘Estimation of the atmospheric emissions of trace elements from anthropogenic sources in Europe’, Atmos. Environ. 18, 41–50.
Pacyna, J. M., Semb, A. and Hanssen, J. E.: 1984, ‘Emissions and long-range transport of trace elements in Europe’, Tellus 36, 163–178.
Padmanabhamurty, B. and Gupta, R. N.: 1977, ‘Particulate pollution in Delhi due to Indraprastha power plant’, Indian J. Met. Hydrol. Geophys. 28, 375–384.
Palit, A., Gopal, R., Dube, S.K. and Mandal, P. K.: 1991, ‘Characterisation and Utilisation of Coal Ash in the Context of Indian Super Thermal Power Stations’, in Sahu, K. C. (ed.), Proc. International Conference on Environmental Impact of Coal Utilization, 1991, Bombay, India, pp. 153–164.
Palit, A., Gopal, R., Roy, D. N. and Jain, S. K.: 1991, ‘Leaching Characteristics of Coal Ash’, in Sahu, K. C. (ed.), Proc. International Conference on Environmental Impact of Coal Utilization, 1991, Bombay, India, pp. 219–238.
Patel, C. B. and Pandey, G. S.: 1986, ‘Alkalinization of soil through thermal power plant fly ash fallout’, Sci. Total Environ. 57, 67–72.
Patel, C. B. and Pandey, G. S.: 1987, ‘Permeation of some toxic elements in soil horizon through thermal power plant flyash fallout’, Indian J. Environ. Hlth. 29, 26–31.
Pfeiffer, W. C., Fiszman, M., Malm, O. and Azcue, J. M.: 1986, ‘Heavy metal pollution in the Paraibo do Sul river, Brazil’, Sci. Total Environ. 58, 73–79.
Phung, H. T., Lund, L. T., Page, A. L. and Bradford, G. R.: 1979, ‘Trace elements in fly ash and their release in water and treated soils’, J. Environ. Quality 8, 171–175.
Que Hee, S. S., Finelli, V., Fricke, F. L. and Wolnik, K. A.: 1982, ‘Metal content of stack emissions, coal and fly ash from some eastern and western power plants in the USA as obtained by ICPAES’, Intern. J. Environ. Anal. Chem. 13, 1–18.
Sakata, M.: 1987, ‘Movement and neutralisation of alkaline leachate at coal ash disposal sites’, Environ. Sci. Tech. 21, 771–777.
Sharma, C. B., Ghose, N. C., Bhaduri, S. K. and Kumar, P.: 1991, ‘Contamination of River Ganga by Fly Ash from Thermal Power Plant at Barauni Industrial Complex, Bihar’, in Sahu, K. C. (ed.), Proc. International Conference on Environmental Impact of Coal Utilization, 1991, Bombay, India, pp. 219–238.
Smith, I.M.: 1987, ‘Trace Elements from Coal Combustion: Emissions, IEA Coal Research, London.
Swaine, D. J., Godbeer, W. C. and Morgan, N. C.: 1984, ‘Environmental Consequences of Coal Combustion’, Rep. NERDDP, No. EG84/315, p. 230.
Thompson, M. and Wood, S.: 1982, Atomic Absorption Spectrometry, Cantle, E. J. (ed.), Elsevier, 261–284.
Torrey, S.: 1978, ‘Coal Ash Utilization: Fly Ash, Bottom Ash and Slag’, Noyes Data Corp., Park Ridge, NJ.
Ure, A. M. and Berrow, M. L.: 1982, ‘The elemental constituents of soils’, Bowen, H. J. M. (Snr. Reporter) Environmental Chemistry, Vol. 2. Specialist Periodical Report, Royal Society of Chemistry, London.
Ward, C. R. (ed.): 1984, Coal Geology and Coal Technology, Blackwell Scientific Publications, Melbourne.
Wolverton, B. C., McDonald, R. C. and Rebeca, C.: 1977, ‘Wastewater Treatment Utilizing Water Hyacinths’, in Proc. 1977 Natn. Conf. on Treatment and Disposal of Industrial Wastewaters and Residue, pp. 205–208.
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Mehra, A., Farago, M.E. & Banerjee, D.K. Impact of Fly Ash from Coal-Fired Power Stations in Delhi, with Particular Reference to Metal Contamination. Environ Monit Assess 50, 15–35 (1998). https://doi.org/10.1023/A:1005860015123
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DOI: https://doi.org/10.1023/A:1005860015123