Abstract
We have developed models of physically-based cloud and ocean surfacesfor use in photochemical models. These surface models are described in termsof a flux albedo and a normalized reflection function.Through these, the dependence of albedo on wavelength, solar zenithangle, cloud optical depth (cloud surfaces) and surface windspeed (ocean surfaces) are allowed for. In addition, the non-Lambertian nature of these surfaces is accounted for.We have integrated these surfacemodels into a multiple scattering radiative transfer model to assess their effects on the stratospheric radiation field and J-values. This was accomplished by comparison with results obtainedusing Lambertian, constant albedo surfaces. Comparisons of stratospheric radiation fields revealed that boththe wavelength and directional dependences of the cloud and oceansurfaces could be large effects.Differences between calculated J-values varied from 0 to 12% depending upon species, solar zenith angle, andheight.The J-values were then used as input for a chemical box model to examine the effects these surfaces had on stratospheric chemistry. Comparisons were made against box model runs using J-values fromconstant surfaces. Overall, the effect was on the order of 10%.Differences in number densities using these different surfacesvaried with latitude, height and species.Runs were made with and without heterogeneous chemistry.
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Anderson, D. E., 1983: The troposphere-stratosphere radiation field at twilight: A spherical model, Planet. Space Sci. 31, 1517–1523.
Anderson, D. E., DeMajistre, R., Lloyd, S. A., and Swaminathan, P. K., 1995: Impact of aerosols and clouds on the troposphere and stratosphere radiation field with application to twilight photochemistry at 20 km, J. Geophys. Res. 100, 7135–7145.
Anderson, D. E., Meier, R. R., and Kumer, J. B., 1980: Improved model of Mie scattering contribution to tropospheric and stratospheric fluxes, Appl. Optics 19, 1230–1231.
Augustsson, T. R. and Levine, J. S., 1982: The effects of isotropic multiple scattering and surface albedo on the photochemistry of the troposphere, Atmos. Environ. 16, 1373–1380.
Benassi, M., Garcia, R. D. M., Karp, A. H., Siewert, C. E., 1984: A high-order spherical harmonics solution to the standard problem in radiative transfer, Astron. J. 280, 853–864.
Chandrasekhar, S., 1960: Radiative Transfer, Dover Publications Inc., New York, pp. 105–126.
Cox, C. and Munk, W. H., 1954: The measurement of the roughness of the sea surface from photographs of the sun’s glitter, J. Opt. Soc. Am. 44, 838–850.
Danilin, M. Yu. and McConnell, J. C., 1995: Stratospheric effects of bromine activation on/in sulfate aerosol, J. Geophys. Res. 100, 11237–11243.
Deirmendjian, D., 1969: Electromagnetic Scattering on Spherical Polydispersions, American Elsevier, New York, pp. 74–83.
DeMore, W. B., Sander, S. P., Golden, D. M., Hampson, R. F., Kurylo, M. J., Howard, C. J., Ravishankara, A. R., Kolb, C. E., Molina, M. J., 1994: Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling, JPL Publication 94-26, Pasadena, CA.
Exton, H. J., Latham, J., Park, P. M., Perry, S. J., and Smith, M. H., 1986: The production and dispersal of marine aerosol, Quart. J. R. Meteorol. Soc. 111, 817–837.
Fitzgerald, J. W., 1991: Marine aerosols: A review, Atmos. Environ. 25A, 533–545.
Gear, C. W., 1971: Numerical Initial Value Problems in Ordinary Differential Equations, Prentice Hall, Englewood Cliffs, N.J.
Hansen, J. E. and Travis, L. D., 1974: Light scattering in planetary atmospheres, Space Sci. Rev. 16, 527–610.
Hennings, I., Matthews, J., Metzner, M., 1994: Sun glitter radiance and radar cross-section modulations of the sea bed, J. Geophys. Res. 99, 16303–16326.
Hofmann, D. J., Oltmans, S. J., Komhyr, W. D., Harris, J.M., Lathrop, J. A., Langford, A. O., Deshler, T., Johnson, B. J., Torres, A., and Matthews, W. A., 1994: Ozone loss in the lower stratosphere over the United States, in 1992–1993: Evidence for heterogeneous chemistry on the Pinatubo aerosol, Geophys. Res. Lett. 21, 65–68.
Jackson, J. D., 1962: Classical Electrodynamics, JohnWiley and Sons, Inc., New York, pp. 279–281.
Kaminski, J.W., McConnell, J. C., and Boville, B. A., 1996: A study of stratospheric chemistry using a 3-D global chemical transport model–I mid-latitude, Accepted by J. Geophys. Res, April.
Lary, D. J. and Pyle, J. A., 1991: Diffuse radiation, twilight, and photochemistry–I, J. Atmos. Chem. 13, 373–392.
de Leeuw, G., 1986: Vertical profiles of giant particles close above the sea surface, Tellus 38B, 51–61.
Liou, K. N., 1980: An Introduction to Atmospheric Radiation, Academic Press, San Diego, pp. 201–216.
Luther, F. M. and Gelinas, R. J., 1976: Effect of molecular multiple scattering and surface albedo on atmospheric photodissociation rates, J. Geophys. Res. 81, 1125–1132.
Madronich, S., 1987: Photodissociation in the atmosphere. 1, Actinic flux and the effects of ground reflection and clouds, J. Geophys. Res. 92, 9470–9752.
McLinden, C. A., McConnell, J. C., Griffioen, E., McElroy, C. T., and Pfister, L., 1996: Estimating the wavelength-dependent ocean albedo under clear-sky conditions using NASA ER-2 spectroradiometer measurements, submitted to J. Geophys. Res..
Nicolet, M., 1984: On the molecular scattering in the terrestrial atmosphere: An empirical formula for its calculation in the homosphere, Planet. Space Sci. 33, 69–80.
Plass, G. N., Kattawar, G.W., and Catchings, F. E., 1984: Matrix operator theory of radiative transfer. 1: Rayleigh scattering, Appl. Optics 12, 314–329.
Ruggaber, A., Dlugi, R., and Nakajima, T., 1994: Modelling radiation quantities and photolysis frequencies in the troposphere, J. Atmos. Chem. 18, 181–210.
Sturm, B., 1980: The atmospheric correction of remotely sensed data and the quantitative determination of suspended matter in marine water surface layers, in A. P. Cracknell (ed.), Remote Sensing in Meteorology, Oceanography, and Hydrology, Ellis Horwood, Chichester, England, pp. 163–197.
Sturm, B., 1981: Ocean colour remote sensing and quantitative retrieval of surface chlorophyll in coastal waters using Nimbus CZCS data, in J. F. R. Gower (ed.), Oceanography from Space, Plenum, New York, pp. 267–279.
Toba, Y., 1961: Drop production by bursting of air bubble films on the sea surface. (III): Study by use of a wind flame, Memoirs Coll. Sci., Univ. Kyoto Ser. A 29, 313–344.
Van de Hulst, H. C., 1957: Light Scattering by Small Particles, Dover Publications Inc., New York, pp. 114–130.
Van de Hulst, H. C., 1980: Multiple Light Scattering; Tables, Formulas, and Applications, Volume 2, Academic Press, San Diego, pp. 477–481.
Vokrouhlicky, D. and Farinella, P., 1995: Specular reflection of sunlight from wavy ocean surfaces and the albedo effect on satellite orbits I. A statistical model, Astron. Astrophys. 298, 307–322.
Wiscombe, W. J., 1978: On initialization, error and flux conservation in the doubling method, J.Q.S.R.T. 16, 637–658.
World Meteorological Organization (WMO), 1985: Atmospheric Ozone 1985, Assessment of our understanding of the processes controlling its present distribution and change, Rep. No. 16, Geneva.
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McLINDEN, C.A., CHARTRAND, D.J., GRIFFIOEN, E. et al. The Impact of Non-Lambertian Wavelength-Dependent Reflecting Surfaces on Stratospheric Radiation and Photochemistry. Journal of Atmospheric Chemistry 26, 29–64 (1997). https://doi.org/10.1023/A:1005775402045
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DOI: https://doi.org/10.1023/A:1005775402045