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Allylation of 5-Methylfurfural Catalyzed by Phase-Transfer Reagents in Aqueous Media

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Abstract

Allylation of 5-methylfurfural with allyl halide and zinc was performed by using quaternary ammonium and phosphonium salts as phase-transfer catalysts. The phosphonium salt showed higher activity than the ammonium salt. Excellent yields were obtained with both catalysts.

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REFERENCES

  1. D. Deng, Z. Lu, K. Wu: Chin. J. Org. Chem., 14, 349 (1994).

    Google Scholar 

  2. C.-J. Li: Tetrahedron, 52, 5643 (1996).

    Google Scholar 

  3. D.A. Russo: Chem. Ind., 64, 405 (1996).

    Google Scholar 

  4. K. Tashiro, K. Tanaka: Eur. Pat. Appl., EP 247 5896.

  5. G. Pincatelli, A. Scottri, G. David, et al.: Tetrahedron, 34, 2775 (1978).

    Google Scholar 

  6. T.A. Killinger, N.A. Boughton, T.A. Ruge, J. Wilinsky: J. Organomet. Chem., 124, 131 (1977).

    Google Scholar 

  7. C. Petrier, L. Luche: J. Org. Chem., 50, 910 (1985).

    Google Scholar 

  8. B. Sain, D. Prajapati, J. Sandhu: Tetrahedron Lett., 33, 4795 (1992).

    Google Scholar 

  9. X.-R. Li, T.-P. Loh: Tetrahedron: Asym., 7, 1535 (1996).

    Google Scholar 

  10. M. Wada, H. Ohki, K.Y. Akiba: Bull. Chem. Soc. Jpn., 63, 1738 (1990).

    Google Scholar 

  11. P.-D. Ren, Q.-H. Jin, Z.-P. Yao: Synth. Commun., 27, 2761 (1997).

    Google Scholar 

  12. C.-J. Li, T.-H. Chan: Tetrahedron Lett., 32, 7017 (1991).

    Google Scholar 

  13. K. Tashiro, K. Tanaka: Jpn. Kokai Tokkyo Koho, JP 63 30 480.

  14. K. Tashiro, K. Tanaka: Jpn. Kokai Tokkyo Koho, JP 63 35 569.

  15. T. Imai, S. Nishida: Synthesis, 395 (1993).

  16. H. Mattes, C. Benezra: Tetrahedron Lett., 26, 5697 (1985).

    Google Scholar 

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Li, Z., Pan, G., Zheng, Z. et al. Allylation of 5-Methylfurfural Catalyzed by Phase-Transfer Reagents in Aqueous Media. Reaction Kinetics and Catalysis Letters 69, 77–82 (2000). https://doi.org/10.1023/A:1005668120838

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  • DOI: https://doi.org/10.1023/A:1005668120838

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