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Side Reactions in the Liquid-Phase Cyclohexanone Ammoximation

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Abstract

Influence of metal ions on hydrogen peroxide decomposition on the liquid-phase ammoximation of cyclohexanone was studied in homogeneous and heterogeneous (over titanium silicalite) conditions. The latter reaction is accompanied by side reactions, which deactivate the catalyst. Deactivation behavior is discussed.

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REFERENCES

  1. J.N. Armor: J. Catal., 70, 72 (1981).

    Google Scholar 

  2. P. Roffia, G. Leofanti, A. Cesana, M. Mantegazza, M. Padovan, G. Petrini, S. Tonti, P. Gervasutti, R. Varagnolo: Chim. Ind. Milan, 72, 598 (1990).

    Google Scholar 

  3. M. Taramasso, G. Perego, B. Notari: US 4,410,501; 1983.

  4. N.V. Kul'kova, V.G. Kotova, M.Yu. Kvyatkovskaya, D.Yu. Murzin: Khim. Prom. Rus., 7, 347 (1995), Russian Chem. Ind., 27, N7, 11 (1995).

    Google Scholar 

  5. N.V. Kul'kova, V.G. Kotova, M.Yu. Kvyatkovskaya, D.Yu. Murzin: Chem. Eng. Technol., 20, 43 (1997).

    Google Scholar 

  6. D.Yu. Murzin, N.V. Kul'kova, V.G. Kotova, M.Yu. Kvyatkovskaya: Kinet. Katal., 39, 763 (1998).

    Google Scholar 

  7. V.G. Kotova, N.V. Kul'kova, M.Yu. Kvyatkovskaya, D.Yu. Murzin: Khim. Prom. Rus., 3, 3 (1997).

    Google Scholar 

  8. N.V. Kul'kova, M.Yu. Kvyatkovskaya, D.Yu. Murzin: Khim. Prom. Rus., 11, 721 (1997).

    Google Scholar 

  9. M.A. Mantegazza, A. Cesana, M. Pastori: Topics in Catalysis, 3, 327 (1996).

    Google Scholar 

  10. Ya.M. Kolotyrkin, G.M. Florianovich, A.I. Kasperovich A.I. in Accounts of science and technology (corrosion and corrosion protection) 8, 3 (1981).

    Google Scholar 

  11. Ch. Rachev, S. Stefanova: Reference book on corrosion. Mir, Moscow 1982.

    Google Scholar 

  12. S. Rondon, M. Houlla, D.M. Hercules: Surface Interface Analysis, 26, 329 (1998).

    Google Scholar 

  13. Kurtenacker, F.Z. Werner: Anorg. Allgem. Chem., 4, 333 (1927).

    Google Scholar 

  14. G. Fornasari, F. Trifirò: Catalysis Today, 41, 443 (1998).

    Google Scholar 

  15. E.N. Kovaleva, A.G. Vandilo, N.M. Dyatlova, V.Ya. Temkina: Dokl. AN RAN, 352, 634 (1997).

    Google Scholar 

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Kul'kova, N.V., Kotova, V.G., Kvyatkovskaya, M.Y. et al. Side Reactions in the Liquid-Phase Cyclohexanone Ammoximation. Reaction Kinetics and Catalysis Letters 69, 95–104 (2000). https://doi.org/10.1023/A:1005649027658

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  • DOI: https://doi.org/10.1023/A:1005649027658

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