Abstract
Pseudo-first order rate constants (kobs) obtained for the reaction of ionized phenyl salicylate (PS-) with anionic DL-proline (Prl-) at a constant [NaOH] and [CTABr] (where CTABr represents cetyltrimethylammonium bromide) and 35°C, show a linear increase with increasing total concentration of Prl-; Nucleophilic second-order rate constants (kn obs) for the reactions of Prl- with PS- reveal a nearly 5-fold decrease with the increase in [CTABr] from 0.0 to 0.01 M.
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Khan, M.N., Arifin, Z. & Yusoff, M.R. Effects of Cationic Micelles on the Rate of Intramolecular General Base-Catalyzed Reaction of Ionized Phenyl Salicylate with DL-Proline. Reaction Kinetics and Catalysis Letters 69, 83–90 (2000). https://doi.org/10.1023/A:1005644909911
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DOI: https://doi.org/10.1023/A:1005644909911