Abstract
The apparent molar volumes and adiabatic compressibilities of 18-Crown-6, 15-Crown-5, 12-Crown-4, tetraglyme, and triglyme were measured at 25°C in H2O and D2O. The contribution of the -CH2CH2O- group to the limiting partial molar volumes and compressibilities of cyclic and open-chain ethers in both solvents are compared and solvent isotope effects calculated. It is concluded, based on the compressibility results, that there is a subtle difference between the hydration of the ethene oxde group in cyclic and open-chain ethers and that this difference persists in D2O. These results indicate that the calculation of limiting apparent molar compressibilities using additivity schemes will have to account for whether the group is in a cyclic or open-chain compound.
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Bernal, P., McCluan, J. Apparent Molar Volumes and Adiabatic Compressibilities of Crown Ethers and Glymes in H2O and D2O at 25°C. Journal of Solution Chemistry 30, 119–131 (2001). https://doi.org/10.1023/A:1005248509674
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DOI: https://doi.org/10.1023/A:1005248509674