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Polarographic Determination of Methanediol Deprotonation Constants in Alkaline Solutions of Various Ionic Strengths

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Abstract

Methanediol deprotonation was studied in alkaline H2O and D2O solutions at various ionic strengths by dc-polarography. The results obtained show a trend of decreasing pKa of up to 1.5 units with increase in solution ionic strength from 0.1 to 1.0 mol-dm-3.

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Authors
  1. E. Norkus
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  2. R. Pauliukaitė
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Norkus, E., Pauliukaitė, R. Polarographic Determination of Methanediol Deprotonation Constants in Alkaline Solutions of Various Ionic Strengths. Journal of Solution Chemistry 30, 55–66 (2001). https://doi.org/10.1023/A:1005206010503

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