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Association Model and Its Representation of Phase Equilibria and Excess Enthalpies of Alcohol, Aniline, and Acetonitrile Mixtures

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Abstract

An association model is presented to describe vapor–liquid equilibria,liquid–liquid equilibria, and excess enthalpies of binary and ternary liquid solutionscontaining alcohols, aniline, and/or acetonitrile using the concepts of linearself-association of associated components and of solvation between unlike molecules.Calculated results also show that the model works well in representing thethermodynamic properties for alcohol + aniline, alcohol + acetonitrile, andalcohol + alcohol mixtures.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Division of Physical Sciences, Kanazawa University, 40-20, Kodatsuno 2-chome, Kanazawa, Ishikawa, 920-8667, Japan

    Isanu Nagata

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  1. Isanu Nagata
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  2. Kazuhiro Tamura
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  3. Kaoru Tada
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  4. Fumihiro Nishikawa
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Nagata, I., Tamura, K., Tada, K. et al. Association Model and Its Representation of Phase Equilibria and Excess Enthalpies of Alcohol, Aniline, and Acetonitrile Mixtures. Journal of Solution Chemistry 29, 815–835 (2000). https://doi.org/10.1023/A:1005148214261

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