Abstract
Densities and viscosities were experimentally determined in the whole range ofcomposition at 25°C for the ternary system diethylamine(1) + ethyl acetate(2)+ n-heptane(3) and for the three corresponding binary systems. Excess molarvolumes and excess viscosities were calculated for the binaries and the ternarysystems. Results were fitted and predicted with expressions from the literatureand are analyzed to gain insight about liquid mixture interactions.
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REFERENCES
S. Aznarez, L. Mussari, and M. A. Postigo, J. Chem. Eng. Data, 38, 270 (1993).
S. Aznarez, L. Mussari, and M. A. Postigo, Monatsh. Chem. 125, 241 (1994).
J. A. Riddick, W. S. Bunger, and T. K. Sakano, Organic Solvents:Techniques of Organic Chemistry, Vol II, 4th edn. [Wiley (Interscience), New York, 1986].
(Thermodynamic Tables:Hydrocarbons and Non-hydrocarbons, 1993). Thermodynamics Research Center, The Texas A&M University System College Station, Texas. TRC
O. Redlich and A. T. Kister, Ind. Eng. Chem. 40, 345 (1948).
R. K. Singh, S. P. Sharma, and S. Aggarwal, Fluid Phase Equilibr. 18, 333 (1984).
Y. Cibulka, Collect Czech. Commun. 47, 1414, (1982).
Y. Nagata and K. Tamura, J. Chem. Eng. Data 33, 283, (1988).
K. C. Chou and Y. A. Chang, Verh. Bunsenges Phys. Chem. 93, 735 (1989).
C. C. Tsao and J. M. Smith, Chem. Eng. Progr. Symp. 7, 107 (1953).
K. T. Jacob and K. Fitzner, Thermochim. Acta 18, 197 (1977).
F. Kohler, Monatsh. Chem. 91, 738 (1960).
R. P. Rastogi, J. Nath, and S. S. Das. J. Chem.Eng.Data 22, 249 (1977).
N. Radojkovic, A. Tasic, D. Grozdanic, B. Djorjevic, and M. Malic J. Chem. Thermodyn. 9, 349 (1977).
J. M. Prausnitz, R. N. Lichtenthaler, and E. Azevedo, Molecular Thermodynamics of Fluid-Phase Equilibria, 2nd edn., (Prentice Hall, Englewood Cliffs, NJ, 1986).
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Lillo, P., Mussari, L. & Postigo, M.A. Excess Molar Volumes and Excess Viscosities of the Ternary System Diethylamine(1) + Ethyl Acetate(2) + n-Heptane(3) at 25°C. Journal of Solution Chemistry 29, 183–197 (2000). https://doi.org/10.1023/A:1005125332005
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DOI: https://doi.org/10.1023/A:1005125332005