Abstract
Historically, solid waste from chromite ore processing has been disposed of at a number of sites in Glasgow, Scotland. Leachate from these sites has been implicated as a source of chromium (Cr) contamination to both groundwaters and stream waters in the south east area of the city. In this study, chromium speciation has been determined in ground-, stream-, river- and pore waters, to assess the extent of contamination and the associated risk. The speciation of chromium is important, as the trivalent species of chromium (Cr(III)) is an essential form of the element, while hexavalent chromium (Cr(VI)) is a known carcinogen to humans via inhalation. Concentrations of total chromium have also been determined in sediments from the River Clyde, to assess the significance of local concentrations relative to those elsewhere in the catchment. High concentrations of Cr(VI) were found in groundwaters and streamwaters in the area immediately surrounding the contaminated sites, and high concentrations of chromium were also found in River Clyde sediments downstream of these sites. However, these concentrations rapidly decrease away from the chromium-contaminated south eastern side of the city. Data from porewaters suggest that some reduction of Cr(VI) occurs naturally in the sediments, indicating that the risk posed by high concentrations of Cr(VI) should be decreased over the longer term.
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Andrle, C. M. and Broekaert, J. A.: 1993, Fres. J. Anal. Chem. 346, 653.
Bartlett, R. J.: 1991, Env. Health Perspectives 92, 17.
Bubris, B. P., Straka, M. R. and Pacey, G. E.: 1983, Talanta 30, 841.
Burke, T., Fagliano, J., Goldoft, M., Hazen, R. E., Iglewicz, R. and McKee, T.: 1991, Env. Health Perspectives 92, 131.
Byrdy, F. A., Olsen, L. K., Vela, N. P. and Caruso, J. A.: 1995, J. Chromatog. 712, 311.
CRC Press Inc.: 1991, Handbook of Chemistry and Physics, Ann Arbor, Boston.
Dionex Corporation: 1991, Determination of Chromium by Ion Chromatography, Technical Note 24, Sunnyvale.
Fendorf, S. E.: 1995, Geoderma 67, 55.
Fleming, G.: 1991, Recycling Derelict Land, Thomas Telford, London.
Gallagher, S., Hursthouse, A., Whalley C., Murney, G. and Rowlatt, S.: 1997, Chromium Contamination Field Trials – South east Glasgow, Final report for Glasgow City Council and Dames and Moore.
Gammelgaard, B., Jons, O. and Neilsen, B.: 1992, Analyst 117, 637.
Grasshoff, K.: 1976, Methods of Seawater AnalysisVerlag Chemie, Weinheim.
Greenwood, N. N. and Earnshaw, A.: 1984, Chemistry of the Elements, Pergamon Press, Oxford.
Hirata, S., Umezaki, Y. and Ikeda, M.: 1989, Anal. Chem. 58, 2602.
Hursthouse, A. S., Iqbal, P. and Denman, R.: 1993, Analyst 118, 1461.
Hursthouse, A. S., Adamczyk, M., Adamczyk, L., Smith, F. J. and Iqbal, P.: 1994, Mar. Poll. Bull. 28, 765.
Jeffries, R. and Hamilton, G. S.: 1994, Contamination Investigation of 15 Sites in South and South East Glasgow, Known or Suspected to be Contaminated by Cr Waste, for Glasgow City Council.
Jen, J.-F., Ou-Yang, G.-L., Chen, C.-S. and Yang, S.-M.: 1993, Analyst 118, 1281.
Kabasakalis, V.: 1993, Anal. Lett. 26, 2269.
Lewis, V. D., Nam, S. H. and Urasa, I. T.: 1989, J. Chromatog. Sci. 27, 468.
van Loon, J. C., Radzivk, B., Khan, N., Lichwa, J., Fernandez, F. K. and Karker, J. D.: 1977, At. Absorpt. Newsl. 16, 79.
Loring, D. H.: 1991, Ices J. Mar. Sci. 48, 101.
Mance, G., Brown, V. M., Gardiner, J. and Yates, J.: 1984, Proposed Environmental Quality Standards for List II Substances in Water – Chromium, WRc TR207, Medmenham.
Murray, J. W., Spell, B. and Paul, B.: 1983 in C. S. Wang <nt>et al. (eds)</nt>, Trace Metals in Seawater, NATO Conf. Ser. IV, Plenum Press, New York.
Nakayama, E., Kuwamoto, T., Tsurubo, S. and Fujinaga, T.: 1981, Anal. Chim. Acta 130, 401.
Naranjit, D., Thomassen, Y. and van Loon, J. C.: 1979, Anal. Chim. Acta 110, 307.
Nieboer, E. and Shaw, S. L.: 1988 in J. O. Nriagu and E. Nieboer <nt>(eds)</nt>, Chromium in the Natural and Human Environments, John Wiley, New York.
Richard, F. C. and Bourg, A. C.: 1991, Wat. Res. 25, 807.
Royal Commission on Environmental Pollution: 1996, Sustainable Use of Soil, HMSO, London.
Rowlatt, S. M. and Lovell, D. R.: 1994, Mar. Poll. Bull. 28, 324.
Smith, R. E.: 1988, Ion Chromatography Applications, CRC Press, Boca Raton.
Subramanian, K. S.: 1988, Anal. Chem. 60, 11.
Tande, T., Pettersen, J. E. and Torgrimsen, T.: 1980, Chromatographia 13, 607.
Ure, A. M. and Davidson, C. M.: 1995, Chemical Speciation in the Environment, Blackie Academic and Professional, Glasgow.
Yassi, A. and Nieboer, E.: 1988, in J. O. Nriagu and E. Nieboer <nt>(eds)</nt>, Chromium in the Natural and Human Environments, John Wiley, New York.
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Whalley, C., Hursthouse, A., Rowlatt, S. et al. Chromium speciation in natural waters draining contaminated land, Glasgow, U.K.. Water, Air, & Soil Pollution 112, 389–405 (1999). https://doi.org/10.1023/A:1005017506227
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DOI: https://doi.org/10.1023/A:1005017506227