Abstract
It is known from the literature that the reaction 2 NO2(aq) + Cl-(aq) → NO3-(aq) + ClNO(g) takes place in the presence of NO2 and sea salt aerosol. This work indicates that the reaction is first order in Cl- and second order in NO2(aq) and the rate coefficient was determined to be 8.9 ± 2.1) × 1010 M-2 s-1 at 293 K. The study shows that the formation rate of nitrate in liquid sea salt aerosol is not influenced by pH in the range between 5.1 and 7.5. The uptake of ammonia in liquid sea salt particles in the present experimental system is governed by the rate of the reaction CO2(aq) + H2O → H2CO3. The addition of NH3 to NO2 and dry sea salt particles does not change the extent of nitrate formation in the particles. The dry aerosol shows an unexpected content of ammonium which increases with decreasing relative humidity. The nitrate formation in frozen sea salt particles at 266 K exposed to only NO2, is about 5 times lower than for the corresponding droplets at 293 K.
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Allen, H. C., Laux, J.M., Vogt, R., Finlayson-Pitts, B. J. and Hemminger, J. C.: 1996, J. Phys. Chem. 100, 6371.
Almgren, T., Dyrssen, D. and Strandberg, M.: 1975, Deep-Sea Res. 22, 635.
Atkinson, R., Baulch, D. L., Cox, R. A., Hampson jr., R. F., Kerr, J. A. and Troe, J.: 1991, J. Phys. Chem. Ref. Data. 21, 1125.
Bennett, R. N., Ritchie, P. D., Roxburgh, D. and Thomson, J.: 1953, Trans. Faraday Soc. 49, 925.
Blanchard, D. C. and Woodcock, A. H.: 1957, Tellus 9, 145.
Bongartz, A. and Schurath, U.: 1992, in Peeters, J. (ed.), EUR 14884, Chemical Mechanisms Describing Tropospheric Processes, E. Guyoy SA, Brussels, p. 29.
Chameides, W. L. and Stelson, A. W.: 1992, J. Geophys. Res. 97, 20565.
Chance, E. M., Curtis, A. R., Jones, I. P. and Kirby, C. R., FACSIMILE, A computer program for flow and chemistry simulation, and general initial value problems. UKAEA Harwell Report AERE-R8775, Didcot, 1987.
Chung, T. T., Dash, J. and O'Brien, R. J.: 1978, Proc. 9th Int. Cong. Electron Microsc. 1, 440.
Clegg. S. L. and Brimblecombe, P.: 1986, EOS 67, 877.
Clegg, S. L. and Whitfield, M.: 1995, Geochim. Cosmochim. Acta 59, 2403.
DeMore, W. B., Golden, D. M., Hampson, R. F., Howard, C. J., Kolb, C. E. Kurylo, M. J., Molina, M. J., Ravishankara, A. R. and Sander, S. P.: 1992, Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling. JPL publication 92-20, Pasadena, 1992.
Eldering, A., Solomon, P. A., Salmon, L. G., Fall, T. and Cass, G. R.: 1991, Atmos. Environ. 25A, 2091.
Ferm, M.: 1979, Atmos. Environ. 13, 1385.
Finlayson-Pitts, B. J.: 1983, Nature 306, 676.
Finlayson-Pitts, B. J. and Pitts, Jr., J. N., Atmospheric Chemistry: Fundamentals and Experimental Techniques, John Wiley & Sons, New York, 1986.
Finlayson-Pitts, B. J., Ezell, M. J. and Pitts jr., J. N.: 1989, Nature 337, 241.
Hanneman, A. U., Mitra, S. K. and Prupppacher, H. R.: 1995, J. Atmos. Chem. 21, 293.
Hanson, D. R., Ravishanakra, A. R. and Solomon, S.: 1994, J. geophys. Res. 99D, 3615.
Hitchcock, D. R., Spiller, L. L. and Wilson, W. E.: 1980, W. E.: 1980, Atmos. Environ. 14, 165.
Hisatsume, I. C.: 1984, Can. J. Chem. 62, 945.
Huston, T., Hisatsune, I. C. and Heicklen, L.: 1983, Can. J. Chem. 61, 2077.
Junge, C. E.: 1956, Tellus 8, 127.
Karlsson, R. and Ljungström, E.: 1995, J. Aerosol Sci. 26, 39.
Karlsson, R. and Ljungström, E.: 1996, Environ. Sci. Technol. 30, 2008.
Kindbom, K., Ferm, M. and Sjöberg, K., Swedish Environmental Research Institute, IVL-report: L89/364 (In Swedish with English abstract), Göteborg, 1989.
Leu, M.-T.: 1988, Geophys. Res. Lett. 15, 17.
Levenspiel, O.: 1972, Chemical Reaction Engineering, John Wiley & Sons, New York.
Lindqvist, O., Ljungström, E. and Svensson, R.: 1982, Atmos. Environ. 16, 1957.
Low, R. D.: 1969, J. de Rech. Atmos. 4, 65.
Maeda, M. and Kinjo, Y.: 1991, Denki Kaguku 59, 473.
Mamane, Y. and Gottlieb, J.: 1992, Atmos. Environ. 26A, 1763.
Mertes, S. and Wahner, A.: 1995, J. Phys. Chem. 99, 14000.
Molina, M. J., Tso, T., Molina, L. T. and Wang, F. C. Y.: 1987, Science 238, 1253.
Mouri, H. and Okada, K.: 1993, Geophys. Res. Lett. 20, 49.
Platt, U. and Heintz, F.: 1994, Israel J. Chem. 34, 289.
Ponche, J. L., George, C. and Mirabel, P.: 1993, J. Atmos. Chem. 16, 1.
Pszenny, A. A. P., Keene, W. C. Jacob, D. J., Fan, S., Maben, J. R., Zetwo, M. P., Springer-Young, M. and Galloway, J. N.: 1993, Geophys. Res. Lett. 20, 699.
Robbins, R. C., Cadle, R. D. and Eckhardt, D. L.: 1959, J. Met. 16, 53.
Schroeder, W. H. and Urone, P.: 1974, Envir. Sci. Technol. 8, 756.
Schwartz, S. E. and White, W. H.: 1983, Adv. Envir. Sci. Tech. 12, 1.
Schwartz, S. E.: 1986, in Jaeschke, W. (ed.), NATO ASI Series, Vol. G6, Chemistry of Multi-phase Atmospheric Systems, Springer-Verlag, Heidelberg, p. 415.
Seinfeld, J. H.: 1986, Atmospheric Chemistry and Physics of Air Pollution, John Wiley & Sons, New York.
Singh, H. B. and Kasting, J. F.: 1988, J. Atmos. Chem. 7, 261.
Smith, R. M. and Martell, A. E.: 1976, Critical stability constants, Vol. 4: Plenum Press, New York.
Smith, R. M. and Martell, A. E.: 1989, Critical stability constants, Vol. 6:2nd Supplement, Plenum Press, New York.
Sverdrup, G. M. and Kuhlman, M. R.: 1980, Studies in Environmental Science 8, 245.
Tang, I. N. and Munkelwitz, H. R.: 1993, Atmos. Emviron. 27A, 467.
Tolbert, M. A., Rossi, M. J., Malhotra, R. and Golden, D. M.: 1987, Science 238, 1258.
Vogt, R. and Finlayson-Pitts, B. J.: 1994, J. Phys. Chem. 98, 3747.
Weast, R. C. (ed.): 1970, Handbook of Chemistry and Physics, 50th edition, the Chemical Rubber Company, Cleveland.
Wingenter, O.W., Kubo, M. K., Balke, M. J., Smith, T.W. jr., Blake, D. R. and Rowland, F. S.: 1996, J. Geophys. Res. 101, 4331.
Winkler, T., Goschnick, J. and Ache, H. J.: 1991, J. Aerosol Sci. 22, S605.
Zetzsch, C., Pfahler, G. and Behnke, W.: 1988, J. Aerosol. Sci. 19, 1203.
Zetzsch, C. and Behnke, W.: 1992, Ber. Bunsenges. Phys. Chem. 96, 488.
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Karlsson, R., Ljungström, E. A Laboratory Study of the Interaction of NH3 and NO2 with Sea Salt Particles. Water, Air, & Soil Pollution 103, 55–70 (1998). https://doi.org/10.1023/A:1004972228592
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DOI: https://doi.org/10.1023/A:1004972228592