Abstract
The effect of fluoride (F) on pH and solubility of organic matter (TOC), aluminium (Al), iron (Fe), calcium (Ca), magnesium (Mg) and potassium (K) in soil samples collected near an aluminium smelter in Norway was studied. Increased addition of F to the soil samples led to an increase in pH and concentrations of TOC, Al and Fe in solution. Most of the F and Al in solution were in the forms of ALFx-complexes. K solubility decreased in some soil samples, but there were no consistent effect on the solubility of Ca or Mg. The effect of NaF addition was significantly different from equimolar NaCl-treatments. The concentrations of Al, Fe, TOC and the pH-values were lower, while the concentrations of K, Mg and Ca were higher in the NaCl-treatments than in the NaF-treatments. The results from the experiment imply that F-pollution of soil induces breakdown of Al- and Fe-oxides/hydroxides and solubilize organic material in the soil. This may influence the availability of potentially toxic elements, such as AIFx-complexes, to microorganisms and plant roots.
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Adriano, D. C. and Doner, H. E.: 1982, Bromine, Chlorine, and Fluorine, in Page, A. L., Miller, R. H. and Keeney, D. R. (eds.), Methods of Soil Analysis. Part 2 — Chemical and Microbiological Properties, Second edition, Madison, Wisconsin, U. S. A. pp. 449-483.
Arnesen, A. K. M., Abrahamsen, G., Sandvik, G. and Krogstad, T.: 1995, Sci. Total Environ. 163, 39.
Barrow, N. J. and Ellis, A. S.: 1986, J. Soil Sci. 37, 287.
Bower, C. A. and Hatcher, C. T.: 1967, J. Soil Sci. 103, 151.
Braanaas, T.: 1970, Tidsskr. Skogbruk 78, 379.
Braen, S. N. and Weinstein, L. H.: 1985, Water, Air, and Soil Pollut. 24, 215.
Cameron, R., Ritchie, C. S. and Robson, A. D.: 1986, Soil Sci. Soc. Am. J. 50, 1231.
David, M. B. and Driscoll, C. T.: 1984, Geoderma 33, 297.
Drury, J. S., Ensminger, J. T., Hammonds, A. S. Hollem, J. W., Lewis, E. B., Preston, E. L., Shriner, C. R. and Towill, L. E.: 1980, Reviews of the Environmental Effects of Pollutants, IX. Fluoride. U.S. Environmental Protection Agency, Cincinnati, Ohio, 549 pages.
Elrashidi, M. A. and Lindsay, W. L.: 1986, Soil Sci. 141, 274.
Elrashidi, M. A. and Lindsay, W. L.: 1987, Environ. Pollut. 47, 123.
Ender, F. 1969. ‘The Effects of Air Pollution on Animals', in Proceedings of the first European Congress on the Influence of Air Pollution on Plants and Animals, Wageningen, April 22-27, 1968, Centre for Agricultural Publishing and Documentation, Wageningen, pp. 245-254.
Froger, T.: 1993, Skogforsk 3, 1.
Hani, H.: 1978, Fluoride 11, 18.
Horntvedt, R. and /Oyen, B. H.: 1994, Effekter av fluorider på skog ved norske aluminiumverk. Norsk aluminiumindustri og milj/o (in Norwegian), part 6, 27 pages. Alumuniumindustriens Milj/osekretariat, Oslo, Norway.
Huang, P. M. and Jackson, M. L.: 1965, Soil Sci. Soc. Am. Proc. 29, 661.
Moore, C. S. and Ritchie, S. P.: 1988, J. Soil Sci. 39, 1.
Murray, F.: 1983, Water, Air, and Soil Pollut. 20, 361.
Nestaas, I.: 1971, Luftforurensning, fluorider og aluminiumsverk (in Norwegian), R/oykskaderådet, Oslo, 99 pp.
Polomski, J., Flühler, H. and Blaser, P.: 1982a, J. Environ. Qual. 11, 457.
Polomski, J., Flühler, H. and Blaser, P.: 1982b, J. Environ. Qual. 11, 452.
Rao, D. N. and Pal, D.: 1978. Plant and Soil 49, 653.
Robak, H.: 1969, ‘Aluminium Plants and Conifers in Norway', in Proceedings of the first Europeen Congress on the Influence of Air Pollution on Plans and Animals, Wageningen, April 22-27, 1968, Centre for Agricultural Publishing and Documentation, Wageningen, pp. 27-31.
Schecher, W. D. and Driscoll, C. T.: 1987, Water Res. Res. 23, 525-534.
Singh, B. R.: 1990, Norw. J. Agr. Sci. 4, 239.
Skjelkvåle, B. L.: 1994, Sci. Tot. Environ. 152, 105.
Skjelkvåle, B. L. and Wright, R. F.: 1994, J. of Hydrology 154, 19.
Takmaz-Nisancioglu, S. and Davison, A. W.: 1988, New Phytol. 109, 149.
Van Wensem, J. and Adena, T.: 1991, Environ. Pollut. 71, 239.
Wentzel, W. W. and Blum, W. E. H.: 1992, J. Environ. Anal. Chem. 46, 223.
Årflot, O.: 1981, Fluor og fluorider hos mennesker, dyr og planter (in Norwegian). Landbruksforlaget, Oslo, 198 pp.
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Arnesen, A.K.M. Effect of Fluoride Pollution on pH AND Solubility of Al, Fe, Ca, Mg, K and Organic Matter in Soil from Årdal (Western Norway). Water, Air, & Soil Pollution 103, 375–388 (1998). https://doi.org/10.1023/A:1004921600022
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DOI: https://doi.org/10.1023/A:1004921600022