Abstract
Interface evolution of nanometer scale Au-Ag bimetal film on SiO2 substrate surface during electromigration was investigated by angle resolved X-ray photoelectronspectroscopy (ARXPS). ARXPS spectra showed that a chemical reaction between Au-Ag filmand SiO2 layer occurred at interface, which caused Au, Ag and Si having differentdistribution and chemical states across the film. This result as well as previousobservation by atomic force microscopy (AFM) demonstrate that electromigration of Au-Agbimetal film on SiO2 surface is accompanied with strong interfacial chemicalreaction rather than a simple lateral physical diffusion process.
Similar content being viewed by others
References
H. Gobel and P. Von Blanckenhagen, Surf. Sci. 331-333 (1995) 885.
F. M. D'Heurle and P. S. Ho, in “Thin Films Interdiffusion and Reactions,” edited by J. M. Poate, K. N. Tu and J. W. Mayer (Wiley, New York, 1978) Ch. 8.
M. Paniccia, P. Flinn and R. Reifenberger, J. Appl. Phys. 73 (1993) 8189.
H. Yasunaga and A. Natori, Surf. Sci. Rep. 15 (1992) 209.
L. E. Levine, G. Reiss and D. A. Smith, J. Appl. Phys. 74 (1993) 5476.
G. Reiss and D. A. Smith Idem., Phys. Rev. B48 (1993) 858.
S. Gunther, A. Kolmakov, J. Kovac, L. Casalis, L. Gregoratti, M. Marsi and M. Kiskinova, Surf. Sci. 377-379 (1997) 145.
S. Gunther, A. Kolmakov, J. Kovac, M. Marsi and M. Kiskinova, Phys. Rev. B56 (1997) 5003.
J. Kovac, S. Gunther, A. Kolmakov, M. Marsi and M. Kiskinova, Surf. Rev. Lett. 5 (1998) 605.
F. X. Shi, W. Q. Yao, L. L. Cao and Y. H. Dong, J. Mater. Sci. Lett. 16 (1997) 1205.
J. F. Moulder, W. F. Stickle, P. E. Sobol and K. D. Bomben, in “Handbook of X-ray photoelectron spectroscopy” (Perkin-Elmer Corporation, 1992).
C. J. Santoro, J. Electrochem. Soc. 116 (1989) 1969.
W. G. Petro, T. Kendelewicz, I. Lindau and W. E. Spicer, Phys. Rev. B34 (1986) 7089.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Shi, F.X., Cao, L.L., Yao, W.Q. et al. Electric field induced interfacial reaction of Au-Ag bimetal film on SiO2 surface. Journal of Materials Science 35, 3655–3658 (2000). https://doi.org/10.1023/A:1004886118489
Issue Date:
DOI: https://doi.org/10.1023/A:1004886118489