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CaBa2Cu2FeO6 Phase: Synthesis, Structure, and Mössbauer Spectra

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Abstract

A new phase CaBa2Cu2FeO6 was synthesized by the ceramic procedure (vacuum, 930°C) from Ca2Fe2O5 and BaCuO2 intermediates. The phase is tetragonal and has a 123 structure with unit cell parameters a = b = 0.4089(3) nm, c = 1.2330(8) nm. Based on the Mössbauer data it is concluded that the iron atoms are in the Fe(3+) state and occupy only the Cu(2) sites, i.e., have tetragonal pyramidal surroundings.

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REFERENCES

  1. R. A. Stukan, N. G. Yudina, M. R. Stukan, and E. F. Makarov, Zh. Strukt. Khim., 39, No. 2, 267–274 (1998).

    Google Scholar 

  2. R. A. Stukan, V. E. Prusakov, E. F. Makarov, and A. V. Polyakova, Zh. Neorg. Khim., 43, No. 8, 1246–1250 (1998).

    Google Scholar 

  3. R. A. Stukan, S. V. Korostin, et al., Zh. Strukt. Khim., 41, No. 4, 858–862 (2000).

    Google Scholar 

  4. A. G. Knizhnik, R. A. Stukan, and G. O. Eremenko, Sverkhprovodimost: Fiz., Khim., Tekh., 3, No. 4, 757–762 (1990).

    Google Scholar 

  5. E. F. Bertaut, P. Blum, and A. Sagnieres, Acta Crystallogr., 12, No. 1, 149–153 (1959).

    Google Scholar 

  6. S. Geller, R. W. Grant, U. Gonser, et al., Phys. Lett., 20, No. 2, 115–117 (1966).

    Google Scholar 

  7. R. W. Grant, H. Widersich, S. Geller, et al., J. Appl. Phys., 38, No. 3, 1455–1456 (1967).

    Google Scholar 

  8. T. Takeda, Y. Yamaguchi, S. Tomiyoshi, et al., J. Phys. Soc. Jpn., 24, No. 3, 446–452 (1968).

    Google Scholar 

  9. S. D. Kirik, S. A. Dubkova, and E. V. Elistratova, “Database on diffraction standards of HTSC, Part 1,” Preprint No. 545 F, Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk (1989).

    Google Scholar 

  10. R. A. Stukan and E. F. Makarov, Khim. Fiz., 9, No. 1, 29–43 (1990).

    Google Scholar 

  11. R. A. Stukan, V. E. Prusakov, et al., Sverkhprovodimost: Fiz., Khim., Tekh., 4, No. 12, 2368–2373 (1991).

    Google Scholar 

  12. V. I. Goldanskii and R. H. Herber (eds.), Chemical Applications of Mössbauer Spectroscopy, Academic Press, New York (1968).

    Google Scholar 

  13. R. A. Stukan, Chemical Sciences Doctoral Dissertation, Institute of Chemical Physics, Russian Academy of Sciences, Moscow (1974).

    Google Scholar 

  14. S. V. Korostin, Yu. V. Permyakov, and E. F. Makarov, Fiz. Nizk. Temper., 21, No. 3, 265–269 (1995).

    Google Scholar 

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  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow

    R. A. Stukan, E. F. Makarov & L. G. Mamsurova

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  1. R. A. Stukan
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  2. E. F. Makarov
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  3. L. G. Mamsurova
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Stukan, R.A., Makarov, E.F. & Mamsurova, L.G. CaBa2Cu2FeO6 Phase: Synthesis, Structure, and Mössbauer Spectra. Journal of Structural Chemistry 41, 798–801 (2000). https://doi.org/10.1023/A:1004858118415

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