Abstract
Metastable silver-nickel alloys have been synthesized by chemical wetness and laser-liquid-solid interaction techniques from nitrate and acetate precursors of silver and nickel. Ethylene glycol and 2-ethoxyethanol were used as reductants in the synthesis reactions. Rotating niobium substrates immersed in the liquid precursor were irradiated by a continuos wave CO2 and Nd-YAG laser (λ = 1064 nm). The powders were characterized by x-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and high-resolution transmission electron microscopy (HRTEM). Two-phase alloys containing silver, nickel, and oxygen were fabricated, and the shape of the particles was found to be dependent on laser parameters and the chemical composition of the precursor solution. The synthesis mechanism of non-equilibrium Ag-Ni alloy nanoparticles has been proposed to occur primarily at the laser-liquid-solid interface by a nucleation and growth mechanism.
Similar content being viewed by others
References
L. Ratke and S. Diefenbach, Material Science and Engineering R15(7-8) (1995).
D. Turnbull, Metallurgical Transactions A 12A (1981) 695.
S. H. Liou, S. Malhotra, Z. S. Shan, D. J. Sellmyer, S. Nafis, J. A. Woollarn, C. P. Reed, G. M. Chow and R. J. De Angelis, J. Appl. Phys. 70(10) (1991) 5882.
M. P. Andrews and S. C. O'brien, J. Phys. Chem. 96 (1992) 8233.
S. D. Dahlgren, J. W. Patten and M. T. Thomas, Thin Solid Films 53 (1978) 41.
B. Y. Tsaur, S. S. Lau, Z. L. Liau and J. W. Mayer, Appl. Phys. Lett. 37(4) (1980) 389.
H. Gleitter, Progress in Material Science 33 (1989) 223.
J. L. Moran-Lopez and L. M. Falicov, in “Alloy Phase Diagrams, Vol. 192,” edited by L. H. Bennett, T. B. Massalski, B. C. Giessen, Materials Research Society Symposium Proceedings, Materials Research Society, New York, 1983.
D. W. Hoffman, J. Catal. 27 (1972) 374.
J. J. Burton, E. Hyman and D. G. Fedak, ibid. 37 (1975) 106.
Q. L. J. Gijzeman, ibid. 92 (1985) 409.
S. H. Liou, S. Malhotra, Z. Shan, D. J. Sellmyer, S. Nafis, J. A. Woolam, C. P. Reed, R. J. De Angeliz and G. M. Chow, J. Appl. Phys. 70 (1991) 5882.
J. R. Childress and C. L. Chien, ibid. 70 (1991) 5885.
J. R. Childress, C. L. Chien and M. Nathan, Appl. Phys. Lett. 56 (1990) 95.
G. M. Chow, T. Ambrose, J. Xiao, F. Kaatz and A. Ervin, Nanostructured Materials 2 (1993) 131.
G. M. Chow, L. K. Kurihara, K. M. Kemner, P. E. Schoen, W. T. Elam, A. Ervin, S. Keller, Y. D. Zhang, J. Budnick and T. Ambrose, J. Mater. Res. 10(6) (1995) 1546.
G. M. Chow, T. Ambrose, J. Q. Xiao, M. E. Twigg, S. Baral, A. M. Ervin, S. B. Qadri and C. R. Feng, Nanostructured Materials 1 (1992) 361.
F. Fievet, J. P. Lagier, B. Blin, B. Beaudin and M. Figlarz, Solid State Ionics 32/33 (1989) 198.
A. S. Edelstein, V. G. Harris, L. Kurihara, D. R. Rolison and F. H. Kaatz, “Processing and Properties of Naocrystalline Materials,” edited by C. Suryanarayana, J. Singh and F. H. Froes (The Minerals, Metals and Materials Society 1996).
L. K. Kurihara, G. M. Chow, S. H. Lawrence and P. E. Schoen, “Processing and Properties of Nanocrystalline Materials,” edited by C. Suryanarayana, J. Singh and F. H. Froes (The Minerals, Metals and Materials Society 1996).
T. C. Pluym, T. T. Kodas, Lu-Min Wang and H. D. Glicksman, J. Materials Research 10(7) (1995) 1661.
R. Subramanium, P. E. Denney, J. Singh and M. Ottoni, J. Materials Science (1998) 3471.
D. Poondi, R. Subramanium, M. Ottoni and J. Singh, J. of Materials Synthesis and Processing 6 (1998) 89.
D. Poondi, T. Doobins and J. Singh, Proceedings of the International Conference on “Recent Advances in Metallurgical Processes,” edited by D. H. Sastry, E. S. Dwarakadas, G. N. K. Iyengar and S. Subramanian, Indian Institute of Science, Bangalore, (1997) 711.
T. Dobbins, D. Poondi and J. Singh, Third Pacific RIM International Conference on Advanced Materials and Processing, Honolulu, Hawaii, edited by M. A. Imam, R. DeNale, S. Hanada, Z. Zhong and D. N. Lee (TMS, July 12-16, 1998) p. 2183.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Poondi, D., Singh, J. Synthesis of metastable silver-nickel alloys by a novel laser-liquid-solid interaction technique. Journal of Materials Science 35, 2467–2476 (2000). https://doi.org/10.1023/A:1004765618078
Issue Date:
DOI: https://doi.org/10.1023/A:1004765618078