Abstract
Ni, NiO and LixNi1-xO are the cathodic materials commonly used in molten carbonate fuel cells (MCFCs). Since the instability of the cathode is recognized as a major hindrance to MCFC development, in this report the behaviour of these nickel species in molten alkali carbonates is reviewed, analyzing step by step the processes of lithiation, dissolution and sinterization at cell operating temperatures.
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References
T. Watanabe, T. Abe, Y. Izaki, Y. Mugikura and E. Koda, in Program and Abstracts, Fuel Cell Seminar, San Diego, CA, 1994, p. 446.
N. Q. Minh, J. Power Source 24 (1988) 1.
S. Van Houten, J. Phys. Chem. Solids 17 (1960) 7.
C. E. Baumgartner, J. Amer. Ceram. Soc. 69 (1986) 162.
H. R. Kunz and J. W. Pandolfo, J. Electrochem. Soc. 139 (1992) 1549.
R. D. Pierce, J. L. Smith and R. B. Poeppel, in "Proceedings of the Symposium on Molten Carbonate Fuel Cell Technology," edited by J. R. Selman and T. D. Claar (The Electrochemical Society, Inc., Pennington, NJ, 1984) p. 147.
C. E. Baumgartner and K. P. Zarnoch, Am. Ceram. Soc. Bull. 64 (1985) 593.
E. Antolini, M. Leonini, V. Massarotti, A. Marini, V. Berbenni and D. Capsoni, Solid State Ionics 39 (1990) 251.
M. Murai, K. Takizawa, K. Soejima and H. Sotouchi, J. Electrochem. Soc. 143 (1996) 2481.
W. M. Vogel, L. J. Bregoli, H. R. Kunz and S. W. Smith, in "Proceedings of the Symposium on Molten Carbonate Fuel Cell Technology," edited by J. R. Selman and T. D. Claar (The Electrochemical Society, Inc., Pennington, NJ, 1984) p. 443.
P. Tomczyk, G. Mordaski and J. Oblakowski, J. Electroanal. Chem. 353 (1993) 177.
T. Nishina, K. Takizawa and I. Uchida, ibid. 263 (1989) 87.
B. Malinowska, M. Cassir, F. Delcorso and J. Devynck, ibid. 389 (1995) 21.
B. Malinowska, M. Cassir and J. Devynck, ibid. 417 (1996) 135.
M. Cassir, B. Malinowska, C. Canevet, L. Sportouch and J. Devynck, J. Power Source 61 (1996) 149.
J. R. Selman and H. C. Maru, in "Advances in Molten Salt Chemistry, Vol. 4," Edited by G. Mamantov and J. Braunstein (Plenum Press, New York, 1983) p. 308.
J. R. Selman and L. G. Marianowski, in "Molten Salt Technology," edited by D. G. Lovering (Plenum Press, New York, 1982) p. 323.
E. Antolini, A. Marini, V. Berbenni, V. Massarotti, D. Capsoni and R. Riccardi, Solid State Ionics 57 (1992) 217.
E. Antolini, J. Mater. Sci. Lett. 12 (1993) 1947.
L. K. Bieniasz and P. Tomczyk, J. Electroanal. Chem. 353 (1993) 195.
R. J. Moore and J. White, J. Mater. Sci.9 (1974) 1393.
K. Hatoh, J. Niikura, E. Yasumoto and T. Gamo, Denki Kagaku 64 (1996) 825.
T. D. Kaun, in "4th International Symposium on Molten Salts," edited by M. Blander, D. S. Newman, G. Mamantov, M. L. Saboungi and K. Johnson (The Electrochemical Society, Pennington, NJ, 1984) p. 489.
C. E. Baumgartner, J. Electrochem. Soc. 131 (1984) 1850.
K. Ota, T. Shinsho and N. Kamiya, Denki Kagaku 55 (1987) 323.
M. L. Orfield and D. A. Shores, J. Electrochem. Soc. 135 (1988) 1662.
D. A. Shores Idem., ibid. 136 (1989) 2862.
J. D. Doyon, T. Gilbert, G. Davies and L. Paetsch, ibid. 134 (1987) 3035.
K. Ota, S. Mitsushima, S. Kato, S. Asano, H. Yoshitake and N. Kamiya, ibid. 139 (1992) 667.
Y. Mugikura, T. Abe, S. Yoshioka and H. Urushibata, ibid. 142 (1995) 2972.
General Electric Company, Development of molten carbonate fuel cell power plant, Final Report, DOE/ET/17019-20, March 1985.
A. Pigeaud, H. C. Maru, L. Paetsch, J. D. Doyon and R. Bernard, in "Proceedings of the Symposium on Porous Electrodes: Theory and Practice," edited by H. C. Maru, T. Katan and M. G, Klein (The Electrochemical Society, Inc., Pennington, NJ, 1984) p. 234.
E. Antolini, J. Power Source 40 (1992) 265.
E. Antolini and M. Giordani, Mater. Lett. 12 (1991) 117.
E. Antolini, Mater. Chem. Phys. 52 (1998) 152.
K. Nakagawa, H. Ohzu, Y. Akasaka and N. Tomimatsu, Denki Kagaku 65 (1997) 231.
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Antolini, E. Behaviour of Ni, NiO and LixNi1−xO in molten alkali carbonates. Journal of Materials Science 35, 1501–1505 (2000). https://doi.org/10.1023/A:1004745332382
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DOI: https://doi.org/10.1023/A:1004745332382