Abstract
This paper deals with the crystallization of MgO during sintering of Si3N4-MgO-CeO2 ceramics. At the initial stage of sintering (1450–1550°C), MgO-CeO2 reacts with free silica to form sufficient liquid phase to densify Si3N4 into nearly full density ceramics; at final stage (1600–1800°C), the crystallization of MgO reduces the amount of glassy phase which is harmful to the high-temperature properties. MgO-CeO2 is found to be an excellent sintering aid for Si3N4.
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References
G. Ziegler, J. Heinrich and G. Wotting, J. Mater. Sci. 22 (1987) 3041.
A. J. Pyzik and D. F. Carroll, Annu. Rev. Mater. Sci. 24 (1994) 189.
Y. Goto and G. Thomas, J. Mater. Sci. 30 (1995) 2194.
S. Y. Yoon, T. Akatsu and E. Uasuda, J. Mater. Res. 11 (1996) 120.
J. T. Smith and C. L. Quakenbush, Amer. Ceram. Soc. Bull. 59 (1980) 529.
C. M. Wang, X. Pan and M. J. Hoffmann, J. Amer. Ceram. Soc. 79 (1996) 788.
W. A. Sanders and D. M. Mieskowski, ibid. 64 (1985) 304.
M. K. Cinibulk, G. Thomas and S. M. Johnson, ibid. 73 (1990) 1606.
M. B. Trigy and K. H. Jack, J. Mater. Soc. Lett. 6 (1987) 407.
H. T. Yang, G. T. Yang and R. Z. Yuan, J. Wuhan University of Technology 11 (1996) 1.
M. J. Hoffmann, MRS Bull. 2 (1995) 28.
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Haitao, Y., Ling, G., Runzhang, Y. et al. Crystallization of MgO during sintering of silicon nitride with magnesia and ceria. Journal of Materials Science 34, 2875–2878 (1999). https://doi.org/10.1023/A:1004687402725
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DOI: https://doi.org/10.1023/A:1004687402725