Abstract
A zero-order model is presented, which allows calculation of the stress distribution in porous epoxies by taking into account the interaction between randomly distributed voids. These results demonstrate that the mean value of the stress concentration factor increases with the volume fraction of voids. This leads to a decrease in sample yield strength. However, the generation of a porous morphology also creates a considerable number of regions where the stress is completely released. The theoretical predictions are in good agreement with experimental results obtained with macroporous epoxies, which were prepared based on the chemically induced phase separation technique, and tested under uniaxial compression.
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References
R. Bagheri and R. A. Pearson, in “25th International SAMPE Technical Conference” (1993) pp. 25–39.
R. A. Bubeck, D. J. Buckley, E. J. Kramer and H. R. Brown, J. Mater Sci. 26 (1991) 6249.
C. B. Bucknall, V. L. P. Soares, H. H. Yang and X. C. Zhang, Macromol. Symp. 101 (1996) 265.
K. Dijkstra, A. van der Wal and R. J. Gaymans, J. Mater Sci. 29 (1994) 3489.
D. Dompas, G. Groeninckx, M. Isogawa, T. Hasegawa and M. Kadokura, Polymer 35 (1994) 4750.
Y. Huang, D. Hunston, A. J. Kinloch and C. Riew, Adv. Chem. Ser. 233 (1993) 1.
A. Lazzeri and C. B. Bucknall, J. Mater Sci. 28 (1993) 6799.
J. P. Pascault, Macromol. Symp. 93 (1995) 43.
R. Schirrer and C. Fond, Rev. Metall. Cah. Inf. Techn. 92 (1995) 1027.
A. F. Lu, Thesis no. 1391, Swiss Federal Institute of Technology (1995).
C. K. Riew and J. K. Gillham, “Rubber-modified thermoset resins”, Advances in Chemistry Series, Vol. 208 (1984).
C. K. Riew, “Rubber toughened plastics”, Advances in Chemistry Series, Vol. 222 (1989).
C. K. Riew and A. J. Kinloch, “Toughened Plastics: Science and Engineering”, Advances in Chemistry Series, Vol. 233 (1993).
A. A. Collyer, “Rubber toughened engineering plastics” (Chapman and Hall, London 1994).
B. J. Cardwell and A. F. Yee, ANTEC (1995) 1519.
C. A. Cruz Jr and S. Havriliak Jr, ibid. (1995) 1521.
Y. Huang and A. J. Kinloch, Polymer 33 (1992) 1330.
L. Boogh, B. Petterson, S. Japon and J. A. MÅnson, in “Proceedings of ICCM”, Vol. 10 (1995) pp. 389–96.
H. J. Sue, J. Mater. Sci. 27 (1992) 3098.
C. B. Bucknall, A. Karpodinis and X. C. Zhang, ibid. 29 (1994) 3377.
R. Schirrer, C. Fond and A. Lobbrecht, ibid. 31 (1996) 6409.
C. Fond and R. Schirrer, Int. J. Fract. 77 (1996) 141.
R. Bagheri and R. A. Pearson, Polymer 36 (1995) 4883.
Idem, ibid. 37 (1996) 4529.
Y. Huang and A. J. Kinloch, J. Mater. Sci. Lett. 11 (1992) 484.
D. Li, A. F. Yee, I. W. Chen and K. Takahashi, J. Mat. Sci. 29 (1994) 2205.
S. Wu, J. Appl. Polym. Sci. 35 (1988) 549.
A. Margolina and S. Wu, Polymer 29 (1988) 2170.
J. Karger-kocsis, Polym. Eng. Sci. 36 (1996) 203.
Idem, Polym. Bull. 36 (1996) 119.
J. Kiefer, J. G. Hilborn, J. A. E. Manson, Y. Leterrier and J. L. Hedrick, Macromolecules 29 (1996) 4158.
J. Kiefer, J. G. Hilborn and J. L. Hedrick. Polymer 37 (1996) 5715.
J. Kiefer, R. Porouchani, D. Mendels, J. B. Ferrer, C. Fond, J. L. Hedrick, H. H. Kausch and J. G. Hilborn in “Microporous and macroporous materials”, MRS Symposium Proceedings, Vol. 431 (1996) 527–32.
J. Kiefer, R. Porouchani, D. Mendels, J. B. Ferrer, C. Fond, J. G. Hilborn and H. H. Kausch, Oberflächen Werkstoffe 5 (1996) 12.
J. Kiefer, H. H. Kausch and J. G. Hilborn, Polym. Bull. 38 (1997) 477.
Y. Huang and A. J. Kinloch, J. Mater. Sci. 27 (1992) 2763.
F. J. Guild and A. J. Kinloch, ibid. 30 (1995) 1689.
J. D. Eshelby, Proc. R. Soc. Lond. 241A (1957) 376.
Idem, ibid. 252A (1959) 561.
Z. A. Moschovidis and T. Mura, J. Appl. Mech. 42 (1975) 847.
N. M. Ferrers, J. Pure Appl. Math. XIV (1877) 1.
F. W. Dyson, ibid. XXV (1891) 259.
J. N. Goodier, ASME Trans. 55 (1933) 39–44.
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Fond, C., Kiefer, J., Mendels, D. et al. Influence of voids on the stress distribution and deformation behaviour of epoxies under uniaxial deformation. Journal of Materials Science 33, 3975–3984 (1998). https://doi.org/10.1023/A:1004652930581
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DOI: https://doi.org/10.1023/A:1004652930581