Abstract
Various titanium suboxide powders have been produced by solid-state reaction between TiO2 powders or TiO2 coated mica and silicon as reducing agent at temperatures below 1000°C in an inert atmosphere. The process leads to blue-grey powders with colour characteristics depending on the composition and the structure of the materials. Titanium suboxides like Ti2O3, γ-Ti3O5, Ti4O7, Ti7O13, Ti8O15 or Ti9O17 are formed during the reduction processes. Calcium chloride as an additive, type of atmosphere as well as temperature have an important influence on the composition and on the colour of the powders. The titanium suboxide powders were characterized by XRD.
Similar content being viewed by others
References
P. W. Gilles and P. G. Wahlbeck, J. Amer. Ceram. Soc. 49 (1966) 180.
S. Andersson, B. CollÉn, U. Kuylenstierna and A. MagnÉli, Acta Chem. Scand. 11 (1957) 1641.
B. Holmberg, ibid. 16 (1962) 1245.
U. Kuylenstierna and A. MagnÉli, ibid. 10 (1956) 1195.
S. Åsbrink and A. MagnÉli, Acta Crystallogr. 12 (1959) 575.
Idem., Naturwissenschaften 43 (1956) 495.
W. J. James, M. E. Strausmanis and T. Ejima, Acta Crystallogr. B33 (1977) 1342.
R. Clark, "Comprehensive Inorg. Chem." Vol. 3 (Pergamon Press, Oxford, New York, 1973).
C. Hauf, Diploma thesis, TH Darmstadt, 1993.
K. D. Franz, K. Ambrosius, S. Wilhelm and K. Nitta (Merck KGaA), WO 93–19131.
L. A. Bursill and B. G. HYde, Prog. Solid State Chem. 7 (1972) 177.
M. E. Bowden, G. V. White, I. W. M. Brown, M. J. Ryan and G. J. Gainsford, Powder Diff. 11 (1996) 60.
R. R. Merritt and B. G. Hyde, Philos. Trans. R. Soc. London 274 (1973) 627.
G. Pfaff, R. Glausch and W. Maus, XXIIth FATIPEC Congr., Budapest, 1994, Proceed. l. p. 56.
Rights and permissions
About this article
Cite this article
Hauf, C., Kniep, R. & Pfaff, G. Preparation of various titanium suboxide powders by reduction of TiO2 with silicon. Journal of Materials Science 34, 1287–1292 (1999). https://doi.org/10.1023/A:1004589813050
Issue Date:
DOI: https://doi.org/10.1023/A:1004589813050