Abstract
Suspensions of ceramic particles in low or high molecular weight polymers are shaped into various three-dimensional parts using various moulding and extrusion technologies. Such bodies are subsequently fired-up and sintered to remove the binder. The utilities of such three-dimensional ceramic bodies depend on the restrictions related to the shapeability of the ceramic suspension, hence to the flow and deformation behaviour of the suspension. In this study, factors affecting the flow and deformation behaviour of a 50% by volume of silicon carbide in a wax binder was investigated. Consistent with the previously observed behaviour of other highly filled materials, the ceramic suspension exhibited viscoplasticity, plug flow and wall slip. Furthermore, flow instabilities associated with the axial migration of the low viscosity binder under the imposed pressure gradient were observed. These results pinpoint to the various difficulties associated with the collection of rheological data and emphasize the relevance of various flow mechanisms, including wall slip and mat formation and filtration based flow instabilities, which would also occur in processing/shaping flows of such ceramic suspensions including extrusion and moulding.
Similar content being viewed by others
References
L. Hench and D. Ulrich, “Ultrastructure processing of ceramics, glass and composites” (John Wiley & Sons, New York, 1984).
Idem., “Science of ceramic chemical processing” (John Wiley & Sons, New York, 1986).
Y. Hasegawa, M. Iimura and S. Yajima, J. Mater. Sci. 15 (1980) 720.
S. Yajima, Amer. Ceram. Soc. Bull. 62 (1983) 893.
D. M. Kalyon and S. Kovenklioglu, Adv. Polym. Tech. 7 (1987) 191.
H. Suwardie, D. M. Kalyon and S. Kovenklioglu, J. Appl. Polym. Sci. 42 (1991) 1087.
H. Yao, S. Kovenklioglu and D. M. Kalyon, Chem. Eng. Commun. 96 (1990) 155.
D. J. Jeffrey and A. Acrivos, AlChE. J. 22 (1976) 417.
H. A. Barnes, J. Non-Newtonian Fluid Mech. 56 (1995) 221.
R. L. Hoffman, Adv. Coll. Interf. Sci. 17 (1982) 161.
A. B. Metzner, J. Rheol. 29 (1985) 739.
M. R. Kamal and A. Mutel, J. Polym. Eng. 5 (1985) 293.
S. A. Khan and R. K. Prud'homme, Rev. Chem. Eng. 3 (1987) 205.
B. K. Aral and D. M. Kalyon, J. Rheol. 41 (1997) 599.
U. Yilmazer and D. M. Kalyon, J. Rheol. 33 (1989) 1197.
D. M. Kalyon, P. Yaras, B. Aral and U. Yilmazer, ibid. 37 (1993) 35.
B. K. Aral and D. M. Kalyon, ibid. 38 (1994).
U. Yilmazer, C. G. Gogos and D. M. Kalyon, Polym. Comp. 10 (1989) 242.
P. Yaras, D. M. Kalyon and U. Yilmazer, Rheol. Acta 33 (1994) 48.
U. Yilmazer and D. M. Kalyon, Polym. Comp. 12 (1991) 226.
D. M. Kalyon, C. Jacob and P. Yaras, Plast. Rubber Comp. Proc. Appl. 16 (1991) 193.
D. M. Kalyon, R. Yazici, C. Jacob, B. Aral and S. Sinton, Polym. Eng. Sci. 31 (1991) 1386.
B. K. Aral and D. M. Kalyon, Plast. Rubber Comp. Proc. Appl. 24 (1995) 201.
D. M. Kalyon, H. GoktÜrk, P. Yaras and B. Aral, SPE ANTEC Tech. Papers 41 (1995) 1130.
F. Gadala-Maria and A. Acrivos, J. Rheol. 24 (1980) 799.
D. Leighton and A. Acrivos, J. Fluid Mech. 275 (1994) 157.
A. Karnis, H. L. Goldsmith and S. G. Mason, Nature 200 (1963) 159.
P. Nott and J. Brady, J. Fluid. Mech. 275 (1994) 157.
A. W. Chow, S. W. Sinton, J. H. Iwamiya and T. S. Stephens, Phys. Fluids 6 (1994) 2561.
R. Phillips, R. C. Armstrong, R. Brown, A. L. Graham and J. Abbott, Phys. Fluids. A 4 (1992) 30.
S. C. Jana, B. Kapoor and A. Acrivos, J. Rheol. 39 (1995) 1123.
D. Doraiswamy, I. L. Tsao, S. C. Danforth, A. N. Beris and A. B. Metzner, in Proceedings of Xth International Congress on Rheology, (1988).
R. Rajkumar, PhD Thesis, State University of New York at Buffalo, 1991.
T. J. Whalen, NASA Contractor Report #180831 (1989).
A. I. Isayev, “Advances in ceramics, ” vol. 21 (American Ceramic Society, Columbus, Ohio, 1987).
J. H. Suwardie, PhD Thesis, Stevens Institute of Technology, 1996.
E. B. Bagley, J. Appl. Phys. 28 (1957) 624.
M. Mooney, J. Coll. Sci. 6 (1951) 162.
P. Yaras, PhD Thesis, Stevens Institute of Technology, 1995.
A. Lawal, S. Railkar and D. Kalyon, J. Mater. Proc. Manuf. Sci. 5 (1996) 57.
A. Lawal and D. M. Kalyon, Int. J. Heat Mass Transfer 40 (1997) 3883.
A. Lawal and D. M. Kalyon, Num. Heat Transfer 26 (1994) 103.
Idem., Polym. Eng. Sci. 34 (1994) 1471.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Suwardie, H., Yazici, R., Kalyon, D.M. et al. Capillary Flow Behaviour of Microcrystalline Wax and Silicon Carbide Suspension. Journal of Materials Science 33, 5059–5067 (1998). https://doi.org/10.1023/A:1004423411227
Issue Date:
DOI: https://doi.org/10.1023/A:1004423411227