Abstract
Fine talc filled high density polyethylene (HDPE) and HDPE/polystyrene (PS) blends were extruded, injection moulded and characterized. Some of the mechanical properties of the talc filled HDPE and talc filled 75/25 HDPE/PS blend were deduced from stress–strain measurements. A comparison between the effect of the talc on the properties of the filled HDPE and filled 75/25 HDPE/PS blend showed that the mineral filler had the same effect on both systems provided that its array in the organic matrix is almost the same in both cases. In fact, the rheological results proved that the dispersion of talc in the HDPE matrix was not really affected by the presence of PS. The study particularly focused on the effect of talc on the ultimate tensile strength of the filled HDPE and that of the filled blend. It has been noted that the brittle nature of PS neutralizes, to a certain extent, the degrading effect of talc on this property. Furthermore, both PS and talc have a complementary effect on the stiffness and the resilience of HDPE/PS/talc blend composites.
Similar content being viewed by others
References
H. T. Mulryan, Minimg Engng. (1993) 1500.
J. A. Radosta and N. C. Trivedi, in “Handbook of fillers for plastics,” edited by H. S. Katz and J. V. Milewsky, (Van Nostrand Reinhold, New York, 1987).
F. Rybnikar, J. Macromol. Sci. Phys. B 19(1) (1981) 1.
A. Einstein, Ann. Physik 17 (1905) 549.
Idem, ibid 19 (1906) 289.
Idem, ibid 34 (1911) 591.
D. G. Thomas, J. Colloid Sci. 20 (1965) 267.
M. Mooney, ibid 6 (1951) 162.
S. H. Maron and P. E. Pierce, ibid 11 (1956) 80.
A. B. Metzner, J. Rheol. 29 (1985) 739.
T. Kitano, T. Kataoka and T. Shirota, Rheol Acta 20 (1981) 207.
B. Pukansky, K. Belina, A. Rockenbauer and F. H. J. Maurer, Composites 25 (1994) 205.
F. Rybnikar, J. Appl. Polym. Sci. 27 (1982) 1479.
B. Wunderlich, in “Macromolecular physics” vol. 2 (Academic Press, New York, 1976).
F. Rybnikar, J. Appl. Polym. Sci. 38 (1989) 1479.
T. Kunori and P. H. Geil, J. Macromol. Sci. Phys. B18 (1) (1980) 93.
E. Guth, J. Appl. Phys. 16 (1945) 20.
H. M. Smallwood, ibid 15 (1944) 758.
Y. Sato and J. Furukawa, Rubb. Chem. Technol. 35 (1962) 857.
J. C. Halpin, J. Compos. Mater. 3 (1969) 732.
S. W. TsaÏ, U.S. Government Report No AD 834851 (1968).
T. B. Lewis and L. E. Nielsen, J. Appl. Polym. Sci. 14 (1970) 1449.
L. E. Nielsen, “Mechanical properties of polymers and composites,” (Marcel Dekker, New York, 1974).
Idem, J. Compos. Mater. 1 (1967) 100.
T. T. Wu, Int. J. Solid Structures 2 (1966) 1.
T. H. Ferrigno, in “Handbook of fillers for plastics,” edited by H. S. Katz and J. V. Milewski (Van Nostrand Reinhold, New York, 1987).
S. Sahu and L. J. Broutman, Polym. Engng. Sci. 12 (1972) 91.
L. E. Nielsen, J. Appl. Polym. Sci. 10 (1996) 97.
L. Nicolais and L. Nicodemo, Int. J. Polymeric Mater. 4 (1974) 229.
R. Lavengood, L. Nicolais and M. Narkis, J. Appl. Polym. Sci. 17 (1973) 1177.
A. M. Riley, C. D. Paynter, P. M. McGenity and J. M. Adams, Plast. and Rubb. Process. and Appl. 14 (1990) 85.
D. M. Bigg, Polym. Compos. 8 (1987) 155.
M. C. Schwarz, J. W. Barlow and D. R. Paul, J. Appl. Polym. Sci. 37 (1989) 403.
H. E. H. Meijer, P. J. Lemstra and P. H. M. Elmans, Makromol. Chem., Macromol. Symp. 16 (1988) 113.
M. C. Schwarz, J. W. Barlow and D. R. Paul, J. Appl. Polym. Sci. 35 (1988) 2053.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Karrad, S., Lopez Cuesta, JM. & Crespy, A. Influence of a fine talc on the properties of composites with high density polyethylene and polyethylene/polystyrene blends. Journal of Materials Science 33, 453–461 (1998). https://doi.org/10.1023/A:1004392318226
Issue Date:
DOI: https://doi.org/10.1023/A:1004392318226