Abstract
Poly(borazinylamine) has been investigated as a binder and as an in situ source material for boron and nitrogen in the frabrication of low volume fraction metal–matrix composites. The representative matrix metals employed in this investigation were aluminium, copper, iron, titanium, nickel and tungsten. The resulting metal–matrix composites contained metal borides and metal nitrides as the ceramic phases in 10.0 mol%, with the exception of copper which does not react with poly(borazinylamine). Although, the composites were prepared at ambient pressure, the aluminium- and titanium-based composites attained close to theoretical densities. The surface analysis of the composites by SEM and XPS showed the presence of a protective oxide layer composed of metal oxide and refractories. © 1998 Chapman & Hall
Similar content being viewed by others
References
K. G. Satyanarayana, R. M. Pillai and B. C. Pai, in “Handbook of Ceramics and Composites”, Vol. 1, “Synthesis and Properties”, edited by N. P. Chereminoff (Marcel Dekker, New York, 1990) pp. 555–95.
“Metal Matrix Composites in the Automative Industry” Materials Edge (Metal Bulletin plc, 16 Lower March, London SEI 7RJ, UK, 1993) pp. 1–34.
T. W. S Chow, A. Kelly and A. Okura, Composites 16 (1985) 187.
P. K. Rohatgi, R. Asthana and S. Das, Int. Metals Rev. 31 (1986) 115.
P. K. Rohatgi, Mod. Cast. 78 (1988) 4750.
C. T. Lynch and J. P. Kershaw, “Metal Matrix Composites” (CRC Press, Cleveland, OH, 1972).
J. White, I. R. Hughes, T.C. Willis and R. M. Jordan, J. Phys. Colloq. C3 (1987) 347.
F. A. Badia, D. F. Mcdonald and J. R. Pearson, AFS Trans 79 (1971) 265.
F. A. Badia and P. K. Rohtagi, AFS Trans. 77 (1969) 402.
B. C. Pai and P. K. Rohtagi, J. Mater. Sci. 13 (1978) 329.
R. Mehrabian, R. G. Rick and M. C. Flemings, Metall. Trans. 5 (1974) 1899.
Md. Hamiuddin, Powder Metall. Int., 19 (1987) 2.
J. E. Allison and G. S. Cole, J. Metals 45 (1993) 19.
B. Boardman, SAE-SP-836 (Society of Automative Engineers, Warrendale, PA, 1990).
M. R. Myers (ed.), “Metal Matrix Composites”, SAE-SP-1010 (Society of Automotive Engineers, Warrendale, PA, 1994).
R. L. Trumper, Metals Mater. 3 (1987) 662.
A. Walker, Mater. Edge 34 (1992) 13.
S. Yajima, T. Shishido and H. Kayano, Nature 264 (1976) 237.
D. Seyferth and P. Czubarow, Chem. Mater. 6 (1994) 10.
C. K. Narula, B. G Demczyk, P. Czubarow and D. Seyferth, J. Amer. Ceram. Soc. 78 (1995) 1247.
J. M. Schwark, Polym. Prepr. 32 (1991) 567.
J. M. Schwark and A. Luckacs, in “Inorganic and Organometallic Polymers II”, edited by P. W.-Neilson, H. A. Allcock and K. J. Wynne (ACS Symposium Series 572, American Chemical Society, Washington, DC, 1994) p. 43.
R. Riedel, G. Passing, R. J. SchÖnfelder and R. J. Brook, Nature 355 (1992) 714.
J. Semen and J. G. Loop, Ceram. Engng Sci. Proc. 12 (1991) 1967.
H. Kodama and T. Miyoshi, Adv. Ceram. Mater. 3 (1988) 177.
T. Erny, M. Siebold, O Jarchow and P. Greil, J. Amer. Ceram. Soc. 76 (1993) 207.
C. K. Narula, R. Schaeffer, R. T. Paine, A. K. Datye and W.F. ammetter, J. Amer. Chem. Soc. 109 (1987) 5556.
R. T. Paine, C. K. Narula, R. O. Schaeffer, D. A. Lindquist and T. T. Borek, US Pat. 5204 295 (1993).
R. R Rye, D. R. Tallant, T. T. Borek, D. A. Lindquist and R. T. Paine, Chem. Mater. 3 (1991) 286.
D. Seyferth, N. Bryson, D. P. Workman and C. A. Sobon, J. Amer. Ceram. Soc. 74 (1991) 2687.
K. Su, M. Nowakowski, D. Bonnell and L. G. Sneddon, Chem. Mater. 4 (1992) 1139.
A. F. Wells, “Structural Inorganic Chemistry”, 3rd Edn (Clarendon Press, Oxford, 1962).
P. Laffitte and P. Grandadam, Compt. Rend. 200 (1935) 1039.
R. Juza and H. Hahn, Z. Anorg. Allgem. Chem. 239 (1938) 282.
F. Lihl and O. Feischl, Metallwirt 8 (1954) 11.
J. Semen and J. G. Loop, Ceram. Engng Sci. Proc. 11 (1990) 1387.
R. Trehan, Y. Lifshitz and J. W. Rabalais, J. Vac. Sci. Technol. A 8 (1990) 4026.
L. Ramqvist, K. Hamrin, G. Johansson, A. Fahlman and C. Nordling, J. Phys. Chem. Solids 30 (1969) 1835.
O. Dugne, S. Prouhet, A. Guette, R. Naslain, R. Fourmeaux, K. Hussein, J. Sevely, C. Guimon, D. Gonbeau and G. Pfister-guillouzo, J. Phys. Colloq. C5 (1989) 334.
D. N. Hendrickson, J. M. Hollander and W. Jolly, Inorg. Chem. 8 (1969) 2642.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Narula, C.K., Czubarow, P. & Seyferth, D. Poly(borazinylamine): an excellent precursor for the preparation of low volume fraction metal-matrix composites containing metal borides and nitrides as ceramic phase. Journal of Materials Science 33, 1389–1397 (1998). https://doi.org/10.1023/A:1004375020410
Issue Date:
DOI: https://doi.org/10.1023/A:1004375020410