Skip to main content
SpringerLink
Log in

Analysis of the Mechanism of Photolysis of Methanol-d4 Solutions of Acetylpropionyl Peroxide with the Use of Chemically Induced Dynamic Nuclear Polarization

  • Published:
Journal of Applied Spectroscopy Aims and scope

Abstract

On the basis of the effects of chemically induced dynamic nuclear polarization of 1H and 13C and the yields of reaction products, the photolysis of methanol-d 4 solutions of acetylpropionyl peroxide is investigated within the temperature interval 193–333 K. Polarization of all the protons of ethylethanoate is detected; it is shown that the latter is formed in several chemical reactions. The role of different excited states of the peroxide in the mechanism of its photolysis is discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. E. D. Skakovskii, A. I. Stankevich, S. A. Lamotkin, L. Yu. Tuchinskaya, and S. V. Rykov, Zh. Obshch. Khim., 66, 881–887 (1996).

    Google Scholar 

  2. E. D. Skakovskii, S. A. Lamotkin, A. I. Stankevich, L. Yu. Tuchinskaya, and S. V. Rykov, Zh. Obshch. Khim., 68, 1028–1033 (1998).

    Google Scholar 

  3. E. D. Skakovskii, S. A. Lamotkin, and L. Yu. Tychinskaya, Zh. Prikl. Spektrosk., 64, 306–311 (1997).

    Google Scholar 

  4. E. D. Skakovskii, L. Yu. Tuchinskaya, L. B. Beresnevich, K. L. Moiseichuk, S. A. Lamotkin, and S. V. Rykov, in: Book of Abstracts of the 10th Int. Conf. on the Chemistry of Organic and Elemental- Organic Peroxides, Moscow (1998), p. 47.

  5. A. P. El'nitskii, Yu. A. Ol'dekop, V. S. Bezborodov, A. I. Stankevich, Yu. V. Glazkov, and E. D. Skakovskii, Vestsi Akad. Navuk BSSR, Ser. Khim. Navuk, No. 2, 58–61 (1976).

    Google Scholar 

  6. E. D. Skakovskii, A. Z. Yankelevich, and S. V. Rykov, Prib. Tekh. E'ksp., No. 1, 137–139 (1988).

    Google Scholar 

  7. J. Calvert and J. Pitts, Photochemistry [Russian translation], Moscow (1968).

  8. H. Rüchardt, Usp. Khim., 37, 1402–1442 (1968).

    Google Scholar 

  9. L. A. Yanovskaya, S. S. Yufit, and V. F. Kucherov, The Chemistry of Acetals [in Russian], Moscow (1975).

  10. J. A. Den Hollander, Chem. Phys., 10, 167–184 (1975).

    Google Scholar 

  11. R. Kaptein, J. Am. Chem. Soc., 94, 6262–6269 (1972).

    Google Scholar 

  12. A. L. Buchachenko, R. Z. Sagdeev, and K. M. Salikhov, Magnetic and Spin Effects in Chemical Reactions [in Russian], Novosibirsk (1978).

  13. A. L. Buchachenko, The Complexes of Radicals and Molecular Oxygen with Organic Molecules [in Russian], Moscow (1984).

  14. N. J. Karch, E. T. Koh, B. L. Whitsel, and J. M. McBride, J. Am. Chem. Soc., 97, 6729–6743 (1975).

    Google Scholar 

  15. P. S. Skell and D. D. May, J. Am. Chem. Soc., 103, 967–968 (1981).

    Google Scholar 

  16. Ya. N. Malkin and E. V. Shepelin, Zh. Obshch. Khim., 57, 1176–1182 (1987).

    Google Scholar 

  17. D. Nonhebel and J. Walton, in: The Chemistry of Free Radicals [Russian translation], Moscow (1977), pp. 213–288.

Download references

Author information

Authors and Affiliations

  1. Institute of Physical and Organic Chemistry, National Academy of Sciences of Belarus, 13 Surganov Str., Minsk, 220072, Belarus

    E. D. Skakovskii, A. I. Stankevich, S. A. Lamotkin, L. Yu. Tychinskaya, G. S. Avrinskii & S. V. Rykov

Authors
  1. E. D. Skakovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. I. Stankevich
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. A. Lamotkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. Yu. Tychinskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. S. Avrinskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. S. V. Rykov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Skakovskii, E.D., Stankevich, A.I., Lamotkin, S.A. et al. Analysis of the Mechanism of Photolysis of Methanol-d4 Solutions of Acetylpropionyl Peroxide with the Use of Chemically Induced Dynamic Nuclear Polarization. Journal of Applied Spectroscopy 67, 770–777 (2000). https://doi.org/10.1023/A:1004191111668

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1004191111668

Search

Navigation