Abstract
The luminescence properties of a series of derivatives of boranes of the type of B10H12[Py(X)]2, C2B9H11Py(X), and C2B9H10BrPy(X) and of the salts of klozo-hydroborate anions B10H10 2− and B12H12 2− with the cations of quaternary pyridine bases (Py(X) is the pyridine and its derivatives) were investigated. The derivatives of decaborane(14) 6,9-bis(pyridine)-nido-decaborane(12) and 6,9-bis(3,4-dimethylpyridine)-nido decaborane(12) are proposed as a base of luminescent materials for recording and visualizing synchrotron radiation within the energy range 10–40 eV. They possess a number of advantages over the base material, namely, sodium salicylate.
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Volkov, V.V., Il'inchik, E.A., Yur'eva, O.P. et al. Luminescence of the Derivatives of Boranes and Adducts of Decaborane(14) of the B10H12[Py(X)]2 Type. Journal of Applied Spectroscopy 67, 864–870 (2000). https://doi.org/10.1023/A:1004167901190
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DOI: https://doi.org/10.1023/A:1004167901190