Abstract
Using the IR spectroscopy method, we have studied the state of water, sulfogroups, and adsorbed methanol in a Fiban K-1 fibrous cationite under different conditions of preparation of a sample. It is shown that on an air-dried cationite protonation of methanol is performed by the ionic pair [(H2n+1O n )+·SO3 −] after vacuum treatment at 20°C and by the ionic pair [H+·SO3 −] after vacuum treatment at 90°C.
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REFERENCES
P. Sykes, Mechanism of Reactions in Organic Chemistry [Russian translation], Moscow (1977).
N. N. Lebedev, Chemistry and Technology of the Main Organic and Oil- Chemical Synthesis [in Russian], Moscow (1973).
B. Kh. Cherches, A. A. Shunkevich, T. N. Belotserkovskaya, and Yu. G. Egiazarov, Zh. Prikl. Khim., 72, No. 4, 623–627 (1999).
T. S. Petkevich, G. K. Berezovik, T. L. Sen'ko, and Yu. G. Egiazarov, Vestsi Nats. Akad. Navuk Belarusi, Ser. Khim. Navuk, No. 1, 56–61 (1999).
V. S. Soldatov, A. I. Pokrovskaya, and R. V. Martsinkevich, Zh. Prikl. Khim., 57, No. 9, 2030–2034 (1984).
M. I. Vinnik and P. A. Obraztsov, Usp. Khim., 59, No. 1, 106–136 (1990).
G. Zundel, Hydration and Intermolecular Interaction [Russian translation], Moscow (1972).
A. V. Johansen, Infrared Spectroscopy and Spectral Determination of Hydrogen Bond Energy. Hydrogen Bond [Russian translation], Moscow (1981).
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Cherches, B.K., Lysenko, G.N. & Egiazarov, Y.G. Investigation of the Fiban K-1 Sulfocationite by the IR Spectroscopy Method. Journal of Applied Spectroscopy 67, 806–811 (2000). https://doi.org/10.1023/A:1004151430324
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DOI: https://doi.org/10.1023/A:1004151430324